Why Does the Equilibrium Constant Depend Only on Temperature?

In summary, the equilibrium constant, K, is determined by the temperature and not the concentration or partial pressure of the reactants and products. When the system is not at equilibrium, the reaction quotient, Q, changes as the concentrations of products and reactants change. However, the system will reach equilibrium when Q = K, and at this point, the ratio of products to reactants remains unchanged. It is important to note that the system adjusts itself to reach equilibrium, rather than being adjusted by an external force.
  • #1
Scharles
16
0
why the equilibrium constant only depending on temperature but not concentration and partial pressure ?

Since K= [product]/[reactants], why the value of K remain the same as [product]or [reactant] increase ?
 
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  • #2
When you add products or reactants Q - so called reaction quotient, defined identically as K - changes its value. However, after that system will react and concentrations of products and reactants will change till Q=K. K describes system at equilibrium, Q describes system at any moment.
 
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  • #3
isn't mean that the ratio of [products] / [reactants] remain unchanged after the system is adjusted to equilibrium ??
 
  • #4
Scharles said:
isn't mean that the ratio of [products] / [reactants] remain unchanged after the system is adjusted to equilibrium ??

System is not adjusted, system adjusts itself. It is not just ratio of products/reactants we are talking about, but reaction quotient, which is more complicated than simple ratio. And finally this is not a correct phrase and I have troubles trying to decipher what you are asking about. Please elaborate.
 
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1. What is the equilibrium constant K?

The equilibrium constant (K) is a numerical value that represents the ratio of product concentrations to reactant concentrations at equilibrium for a given chemical reaction.

2. How is the equilibrium constant K calculated?

The equilibrium constant K is calculated by taking the concentrations of the products, raised to the power of their coefficients, and dividing it by the concentrations of the reactants, also raised to the power of their coefficients. This calculation is only valid when the reaction is at equilibrium.

3. What does a high or low value of equilibrium constant K indicate?

A high value of equilibrium constant K indicates that the reaction favors the formation of products at equilibrium, meaning the products are more stable than the reactants. A low value of equilibrium constant K indicates that the reaction favors the formation of reactants at equilibrium, meaning the reactants are more stable than the products.

4. How does the equilibrium constant K change with temperature?

The equilibrium constant K is affected by changes in temperature. An increase in temperature will generally favor the endothermic reaction, causing an increase in the value of K, while a decrease in temperature will favor the exothermic reaction, causing a decrease in the value of K.

5. Is the equilibrium constant K affected by changes in concentration or pressure?

Yes, the equilibrium constant K is affected by changes in concentration or pressure of the reactants or products. However, the value of K itself does not change, but the value of the concentrations used in the calculation of K will change, resulting in a new value for K.

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