- #1
Ravian
- 42
- 0
what is the practical use of the concept of band gap other than classification between material? can free carrier absorption be manipulated by changing band gaps?
Ravian said:what is the practical use of the concept of band gap other than classification between material? can free carrier absorption be manipulated by changing band gaps?
Ravian said:so the band gap for a particular material is a constant value e.g. 6.1eV for AlN or it can vary. Does not a band structure show many band gaps between different states of electrons? if electrons live in certain orbitals or shells of specific energy then how a band gap is formed i mean how can we determine that band gap lies between what orbitals.
Each orbital changes into a band.Ravian said:i mean how can we determine that band gap lies between what orbitals.
Yes, for a given temperature.so the band gap for a particular material is a constant value e.g. 6.1eV for AlN or it can vary.
Ravian said:if electrons live in certain orbitals or shells of specific energy then how a band gap is formed i mean how can we determine that band gap lies between what orbitals.
Ravian said:what is the practical use of the concept of band gap other than classification between material? can free carrier absorption be manipulated by changing band gaps?
Ravian said:so to sum up i can say when atoms interact to make a solid, their atomic orbitals mix to form two bands of orbitals namely valence band and conduction bands with an energy gap between them where no electronic states exist.
Further, these electronic states are quantized and electronic transitions take place in accordance with pauli’s exclusion principle that is no two electrons of the same spin can occupy same state.
A band gap is an energy range that exists between the valence band and the conduction band in a solid material. It represents the energy level that electrons cannot occupy, creating a gap in the material's energy spectrum.
Band gaps have various practical uses, such as in electronic devices where they can be used to control the movement of electrons and create semiconductors. They are also crucial in the development of solar cells, as they determine the material's ability to absorb and convert light into electrical energy.
Band gaps can be manipulated by altering the composition and structure of a material. Adding impurities, also known as doping, can change the band gap and give the material new properties. Additionally, applying external forces such as pressure or an electric field can also modify a material's band gap.
Free carrier absorption is a phenomenon that occurs when photons of light are absorbed by free electrons in a material, causing them to transition to a higher energy state. This process is essential in the absorption of light in semiconductors, which is necessary for the functioning of solar cells and other optoelectronic devices.
The amount of free carrier absorption in a material is directly related to the band gap. Materials with a smaller band gap have a higher absorption of light and are more efficient at converting it into electrical energy. This relationship is crucial in the development of new materials for solar cells and other optoelectronic applications.