Ionization Potential and Work Function

In summary, Ionization Potential (IP) values do not include the work function of the electron removal process. IP is defined as the energy required to remove the outermost electron from an isolated atom in gaseous state, which does not have a work function. Work function arises from other factors such as crystal structure. The listed IPs for elements were not necessarily measured in the gaseous state, as modern methods use sophisticated equipment and spectroscopy. IP is a quantity independent of temperature, and attaining high accuracy in its measurement is still a challenge.
  • #1
what_are_electrons
Do Ionization Potential values include or exclude the work function of the electron removal process? For example: The IP value for hydrogen is 13.6 eV.

Is the true IP 13.6 eV or 13.6 - WF (ca. 4 eV) = 9.6 eV roughly?
 
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  • #2
No they don't include the work function.

Ionization potential is defined as the energy required to remove the outermost electron from an isolated atom in gaseous state.

An isolated atom in gaseous state does not have any work function.

Work function arises from other factors including the crystal structure etc. etc.
 
  • #3
vinter said:
No they don't include the work function.

Ionization potential is defined as the energy required to remove the outermost electron from an isolated atom in gaseous state.

An isolated atom in gaseous state does not have any work function.

Work function arises from other factors including the crystal structure etc. etc.

Does this mean that all of the IPs listed for all of the elements were measured when the elements were in a gaseous state? If so, what temperature would be used?
Thanks!
 
  • #4
according to quantum theory, since the energy is quantize, the result is independent to the temperature...

let me do a very simple calculation for H atom
[tex] KE \approx kT = 8.617 \times 10^{-5} T (in Kelvin)eV [/tex]

in a room temperature, T=300 degree, KE approximately equal to 10^-2 eV, only a fraction of IP (13.6 eV in your case)... so even if you use classical theory... the error in minimal...
 
  • #5
Though IPs are related to atoms in the gaseous state, they ar NOT usually measured in the gaseous state. The old method is to use Hess' Law of Constant Summation, one of the great applications of which is the Born Haber Cycle. Modern methods include sophisticated equipments and spectroscopy etc. etc.
Ionization Potential is DEFINED as a quantity independent of such things as the temperature. It's like, you consider just an atom with a nucleus and the electrons and forget about what's going on outside it. This definition does create problems because in the laboratory, your apparatus cannot be independent of such other factors. To attain a high accuracy in the measurement of IP is still a challenge.
 
  • #6
OK. Got it. Many thanks for the assist.
 

1. What is ionization potential?

Ionization potential is the amount of energy required to remove an electron from an atom or molecule in its ground state. It is typically measured in electron volts (eV) or kilojoules per mole (kJ/mol).

2. How is ionization potential related to the electron configuration of an atom?

The ionization potential of an atom is directly related to the number of protons in the nucleus and the number and arrangement of electrons in the atom's energy levels. The higher the number of protons and the closer the electrons are to the nucleus, the higher the ionization potential will be.

3. What is the significance of ionization potential in chemical reactions?

The ionization potential of an atom or molecule determines its reactivity and ability to form chemical bonds. Atoms with low ionization potentials are more likely to lose electrons and form positive ions, while atoms with high ionization potentials are more likely to gain electrons and form negative ions.

4. What is work function?

Work function is the minimum amount of energy required to remove an electron from the surface of a solid material. It is a measure of the strength of the bond between the electrons and the material's surface.

5. How does work function affect the emission of electrons from a surface?

The higher the work function of a material, the more energy is required to remove an electron from its surface. This means that materials with high work functions require more energy to emit electrons, making them less likely to emit electrons compared to materials with lower work functions.

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