Johnson-Mehl-Avrami Equation

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In summary, the Johnson-Mehl-Avrami Equation is a mathematical formula used to describe phase transformations in materials and is commonly used in materials science, metallurgy, and engineering. It was first proposed by three scientists in the 1930s and is based on several key assumptions, including homogeneity, isothermality, and a single-step transformation process. It is often used in conjunction with experimental data to determine activation energy and rate constants, but may have limitations in accurately predicting complex transformations or non-isothermal processes.
  • #1
darkelf
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Hello,

Could anyone help shed more light on the Johnson Mehl Avrami equation and how it relates to recrystallization or crystallization? I can't seem to find much on it.

Any information would be appreciated.

Thank you
 
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  • #2
Do you have a specific question? The first link on Google (a Carnegie Mellon lecture) gives the equation, the characteristics, the applications, and the literature references.
 
  • #3
for your question. The Johnson-Mehl-Avrami equation, also known as the Johnson-Avrami-Mehl equation, is a mathematical model used to describe the kinetics of phase transformations, including recrystallization and crystallization. It was first proposed in 1939 by W. A. Johnson and R. Mehl, and later refined by N. Avrami in 1940.

The equation is based on the assumption that the transformation occurs through the nucleation and growth of new phases, and it takes into account the effects of both nucleation and growth rates on the overall transformation kinetics. It is commonly expressed as:

X = 1 - exp[-(kt)^n]

Where X is the fraction transformed, k is the rate constant, t is time, and n is the Avrami exponent. The value of n can vary depending on the specific transformation, but typically ranges from 2 to 4.

The Johnson-Mehl-Avrami equation has been widely used in various fields of science and engineering, including metallurgy, materials science, and geology. It has been shown to accurately describe the kinetics of phase transformations in a variety of materials, making it a valuable tool for understanding and predicting these processes.

I hope this helps to shed some light on the Johnson-Mehl-Avrami equation and its relevance to recrystallization and crystallization. Please let me know if you have any further questions or if I can provide any additional information.
 

1. What is the Johnson-Mehl-Avrami Equation?

The Johnson-Mehl-Avrami Equation is a mathematical formula used to describe the kinetics of phase transformations in materials. It is commonly used in materials science, metallurgy, and engineering to predict the rate of transformation from one phase to another.

2. How is the Johnson-Mehl-Avrami Equation derived?

The Johnson-Mehl-Avrami Equation was first proposed by three scientists - W.A. Johnson, R. Mehl, and R.W. Avrami - in the 1930s. They used a kinetic model based on the assumption that the rate of transformation is proportional to the number of untransformed particles remaining at any given time.

3. What are the key assumptions of the Johnson-Mehl-Avrami Equation?

The Johnson-Mehl-Avrami Equation assumes that the transformation process is homogeneous and occurs uniformly throughout the material. It also assumes that the transformation is isothermal, meaning that the temperature remains constant during the process. Additionally, it assumes that the transformation occurs in a single step without any intermediate stages.

4. How is the Johnson-Mehl-Avrami Equation used in practice?

The Johnson-Mehl-Avrami Equation is often used in conjunction with experimental data to determine the activation energy and rate constant for a particular phase transformation. It can also be used to predict the fraction of transformed material at a given time or temperature.

5. What are the limitations of the Johnson-Mehl-Avrami Equation?

The Johnson-Mehl-Avrami Equation is based on several assumptions and may not accurately describe complex phase transformations in some materials. It also does not take into account any nucleation or growth mechanisms that may affect the rate of transformation. Additionally, it is only applicable to isothermal transformations and may not accurately predict non-isothermal transformations.

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