Looking at reaction force on a molecular level?

In summary, a reaction force is created by the electrostatic interactions between electrons and nucleii of the surface atoms at the points of contact. The potential energy curve of a H2 molecule shows how the force between the atoms decreases until it reaches a minimum, and then becomes repulsive.
  • #1
briton
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Can anyone explain how a reaction force (for example the electrostatc force of the Earth on the stone, and the force of the stone on the earth) works on a molecular level?

what is actually happening to *repel (if it does indeed repel??) the object
 
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  • #2
A couple of thoughts to keep in mind:

1. Nature tends toward equilibrium - or lowest possible energy state.

2. Gravity is mutual - two masses attract each other - equal and opposite. As Gokul corrected me, "Force is a binary operator, F = f(m1,m2). The field due to a more massive object is greater. The force exerted by the Earth on the moon equals the force exerted by the moon on Earth - Newton's Third." Electric/magnetic forces are also mutual - attraction between opposite charges/poles and repulsion between like charges/poles.

briton, as for the earth/stone system, to what electrostatic force do you refer?

Going to the atomic level, the electron fields (and the atomic bonds they form) around the nuclei maintain spacing between nuclei/atoms. Solids are relatively incompressible - i.e. low strains at moderate pressures/compressive stresses (MPa range) - but at high pressures (GPa) interatomic spacing will decrease substantially.

As for measuring atomic forces, this can be done by atomic force microprobes, which have been developed by companies such as IBM. As far as I know, AFM's are applied under vacuum conditions.

High pressures on materials in the laboratory can be applied by diamond anvils - see examples at - http://hannahsmac.magnet.fsu.edu/F_S/high_pressure.html [Broken]

http://www.crystal.vt.edu/crystal/dac.html [Broken]

http://www.hpdo.com/ (website of High Pressure Diamond Optics, Inc. )
 
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  • #3
The origin of a macroscopic reaction force is indeed in the electrostatic interactions between electrons and nucleii of the surface atoms at the points of contact.

The idea is encapsulated in the potential energy curve of a H2 molecule. Below is a plot of the potential energy of a pair of H-atoms as a function of their separation.

[PLAIN]http://epswww.unm.edu/facstaff/zsharp/bio1_files/image008.gif [Broken] [/PLAIN]

As atoms get close, the potential keeps decreasing (a negative potential indicates an attractive force) till it reaches a minimum. As the separation decreases beyond this, the potential increases till it starts becoming positive (top left portion of curve). Now the force between the atoms is repulsive.


For larger atoms than hydrogen, the PE curve is more complex, with several alternating positive and negative regions. Each of these positive regions represents a repulsion. This repulsion is the basis of the reaction force.
 
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1. What exactly is reaction force on a molecular level?

Reaction force on a molecular level refers to the force that is exerted by one molecule on another during a chemical reaction. It is a result of the interactions between atoms and molecules and is essential for understanding the mechanisms of chemical reactions.

2. How is reaction force measured on a molecular level?

Reaction force is typically measured using techniques such as spectroscopy, which allows scientists to observe molecular vibrations and interactions. Other methods, such as molecular dynamics simulations, can also be used to calculate reaction forces.

3. What role does reaction force play in chemical reactions?

Reaction force is crucial for understanding the energetics and kinetics of chemical reactions. It determines the direction and rate of a reaction, as well as the products that are formed. Without considering reaction forces, it is impossible to accurately predict the outcome of a chemical reaction.

4. How do different types of molecules interact with each other on a molecular level?

The interactions between molecules on a molecular level are governed by various forces such as electrostatic interactions, hydrogen bonding, and van der Waals forces. These forces can either attract or repel molecules, depending on their chemical properties.

5. Can reaction force on a molecular level be manipulated for practical applications?

Yes, understanding and manipulating reaction forces on a molecular level is essential for many practical applications, such as drug design, material synthesis, and catalysis. By altering the reaction forces, scientists can control the outcome of chemical reactions and design new molecules with specific properties.

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