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Tsar_183
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Homework Statement
Show explicitly that Entropy as defined by the Gibbs Entropy Formula is extensive. That is, for two independent (noninteracting) systems A and B,
S(A,B) = S(A) + S(B)
where S(A,B) is the entropy of A and B considered as part of a larger system.
Homework Equations
S = -k [itex]\sum[/itex] pi ln(pi)
The Attempt at a Solution
I honestly have no idea where to start! I tried letting pi = 1/Ω, to obtain,
S = k [itex]\sum[/itex] (1/Ω)ln(Ω), and then tried summing S(A) and S(B) together to obtain S(A,B), but it didn't work out. I also tried just summing up S(A) and S(B) without writing in terms of Ω...didn't work either. I then tried,
S = -k [itex]\sum[/itex] pi ln(pi) ==>
S = k [itex]\sum[/itex] (1/Ω) ln(Ω) ==>
S = k (1/Ω) ln(Ω)[itex]\sum[/itex] 1, [itex]\sum[/itex] 1 = Ω
S = k (1/Ω) ln(Ω)Ω
S = k ln(Ω)
and then I summed up S(A) and S(B) which WORKED,
S(A,B) = k ln(Ω(A))+k ln(Ω(B)) = k ln(Ω(A)Ω(B)) = k ln (Ω(A,B)), but I don't think this argument works. Plus the prof derived the Gibbs Entropy Formula from k ln Ω... so I don't think I'm even on the right track! Any ideas or suggestions? Thanks!
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