Chemistry equilibrium question

In summary, the addition of Ar(g) to the reaction 2NOCl(g)<-->2NO(g)+Cl2(g) will not alter the equilibrium as no change has been made to the individual parts of the chemical equation, unless there is a change in pressure or volume.
  • #1
bobbarkernar
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Homework Statement




For the equalibrium: 2NOCl(g)<-->2NO(g)+Cl2(g), delta G=+77.1kJ
Determine in which direction the equilibrium will shift by the following changes.

A) Ar(g) is added to the reaction

Homework Equations





The Attempt at a Solution



My first thought is that this will not alter the equilibrium as no change has been made to the individual parts of the chemical equation. I hope someone could point me in the right direction, if i am wrong or confirm that this is the right conclusion.

Thank you,
 
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  • #2
Are there any other conditions given? Ie constant pressure/volume. Because Argon is an inert gas, and in one of the two conditions, nothing changes. The other one does.

Constant volume, nothing changes. Constant pressure, things will change.
 
  • #3


I can confirm that your initial thought is correct. The addition of Ar(g) to the reaction will not alter the equilibrium as it is an inert gas and does not participate in the reaction. The only factors that can affect the equilibrium of a chemical reaction are changes in temperature, pressure, or the concentrations of the reactants and products. In this case, since no changes have been made to these factors, the equilibrium will remain unchanged.
 

1. What is chemical equilibrium?

Chemical equilibrium is a state in a chemical reaction where the forward and reverse reactions occur at equal rates, resulting in no net change in the concentrations of reactants and products. This means that the system has reached a balance between the reactants and products.

2. How is equilibrium achieved in a chemical reaction?

Equilibrium is achieved when the rate of the forward reaction is equal to the rate of the reverse reaction. This can occur when the concentrations of reactants and products reach a certain level, or when the temperature, pressure, or other factors that affect the reaction are constant.

3. What is the difference between dynamic and static equilibrium in chemistry?

In chemistry, dynamic equilibrium is a state where the rates of the forward and reverse reactions are equal, while the concentrations of reactants and products are constantly changing. On the other hand, static equilibrium is a state where there is no change in the concentrations of reactants and products, but the reactions have not necessarily stopped.

4. How does Le Chatelier's principle apply to chemical equilibrium?

Le Chatelier's principle states that when a system at equilibrium is subjected to a change, the system will shift in a way that counteracts the change and returns to equilibrium. This means that if a stress, such as a change in temperature or pressure, is applied to a chemical equilibrium, the system will adjust to minimize the effect of the stress and maintain equilibrium.

5. How can you calculate the equilibrium constant for a chemical reaction?

The equilibrium constant, represented by K, is calculated by dividing the concentration of products by the concentration of reactants, each raised to their respective coefficients in the balanced chemical equation. The value of K indicates the relative amounts of products and reactants at equilibrium and can be used to predict the direction of the reaction under different conditions.

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