Can Ice Remain After Water Cools to 0°C?

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In summary, the conversation discusses the heat exchange between ice and water and how it affects the state of the system. It is determined that with the given equation, all ice will be melted due to the heat contained in the water after reaching 0 degrees. The definition of qw as "heat still in the water after reaching 0 C" also ensures that all ice will be melted.
  • #1
kieselxeren
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Consider that we have ice and water together ( no heat exchange with surrounding ) and
qi1 = heat required by ice to reach 0 C from ti ( < 0 )
qi2 = heat required by ice at 0 C to convert into water at 0 C
qw = heat that can be released by water after reaching 0 C from tw ( > 0 )

if ( qi1 + qi2 ) <= qw

can there be a case when some ice is left in the system ?
 
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  • #2
No, your equation says that there is enough heat in the water to after it has reached 0 degrees to melt any ice in the water. In fact, all heat the water loses while dropping to 0 degrees would also contribute to melting the ice.

If you had set qw as the "heat contained by the water at tw" degrees and qi1+ qi2= qw then you would be "right on the verge" where whether there was a tiny amount of ice or not would depend on local effects. But is qi1+ qi2< qw or with your definition of qw as "heat still in the water after reaching 0 C", all ice will be melted.
 
  • #3


Yes, it is possible for some ice to be left in the system in this scenario. This would occur if the total heat required by the ice to reach 0°C and convert into water at 0°C (qi1 + qi2) is less than or equal to the amount of heat that can be released by the water after reaching 0°C (qw). In this case, there would still be some remaining ice in the system, as not all of it has melted into water due to the limited amount of heat available from the water. This can happen if the initial temperature of the ice (ti) is very low or if the amount of ice present is large compared to the amount of water.
 

1. What is the water-ice equilibrium?

The water-ice equilibrium is the state in which water and ice coexist at a certain temperature and pressure. It is a dynamic equilibrium, meaning that there is a constant exchange of molecules between the liquid and solid phases.

2. How does temperature affect the water-ice equilibrium?

As temperature increases, the equilibrium shifts towards the liquid phase, with more water molecules transitioning from ice to liquid. Conversely, as temperature decreases, the equilibrium shifts towards the solid phase, with more water molecules transitioning from liquid to ice.

3. What factors can influence the water-ice equilibrium?

The water-ice equilibrium can be influenced by temperature, pressure, and the presence of impurities. For example, adding salt to water can lower the freezing point and shift the equilibrium towards the liquid phase.

4. How does pressure affect the water-ice equilibrium?

Increasing pressure can also shift the water-ice equilibrium towards the liquid phase. This is because higher pressure increases the melting point of ice, making it easier for water molecules to transition from solid to liquid.

5. Why is the water-ice equilibrium important in environmental science?

The water-ice equilibrium is important in environmental science because it plays a significant role in many natural processes, such as the formation of glaciers and the melting of sea ice. It also affects the distribution of organisms in aquatic ecosystems and can impact climate change and global water cycles.

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