What is water of crystallisation?

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In summary, the conversation discusses whether water molecules in a crystal lattice act as ligands or are simply trapped within the lattice. It is found that both scenarios are possible, with the crystal lattice containing specific vacancies for water molecules to fit in. The conversation also explores why certain metal salts, such as lithium, form water of crystallisation more readily than others and what causes some salts to be more deliquescent than others.
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jd12345
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Does the water molecule act as a ligand or is it trapped in the crystal lattice somehow?

If it is trapped in the crystal lattice then why it is found in a specific ratio? And why some metal salts like lithium form water of crystallisation more than other metal salts?
 
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  • #2
jd12345 said:
Does the water molecule act as a ligand or is it trapped in the crystal lattice somehow?

Both scenarios possible.

If it is trapped in the crystal lattice then why it is found in a specific ratio?

Crystal lattice contains well defined number of right sized vacancies that water molecule can fit in.
 
  • #3
Okay, i suppose the d-block elements mostly have water of crystallisaiton as ligands, right? And others like alkali metals in their crystal lattice?

Also what makes some salts like Lithium salts so deliquescent?
 

What is water of crystallisation?

Water of crystallisation is water molecules that are chemically bonded to a crystalline substance. These water molecules are an integral part of the crystal structure and are often included in the chemical formula of the substance.

Why is water of crystallisation important?

Water of crystallisation is important because it affects the physical and chemical properties of a substance. It can also affect the stability and solubility of the substance, and can play a role in its reactions and reactions with other substances.

How is water of crystallisation formed?

Water of crystallisation is formed when a substance in its aqueous form crystallises. During the crystallisation process, water molecules become trapped in the crystal structure and form strong bonds with the substance.

Can water of crystallisation be removed?

Yes, water of crystallisation can be removed through processes such as heating, dehydration, or exposure to dry air. This results in a change in the physical and chemical properties of the substance, as the water molecules are no longer bonded to the crystal structure.

What are some examples of substances with water of crystallisation?

Some examples of substances with water of crystallisation include hydrated salts such as copper sulfate pentahydrate (CuSO4 · 5H2O) and alum (KAl(SO4)2 · 12H2O), as well as minerals like gypsum (CaSO4 · 2H2O) and mirabilite (Na2SO4 · 10H2O).

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