What is the state of matter beyond the critical point?

Indistinguishable liquid and gas"In summary, when transitioning from a gas state to a liquid state by passing through the critical point on a p-T phase diagram, the molecules or atoms may start to form bonds, leading to the concept of an "indistinguishable" liquid and gas. This is analogous to two rooms separated by a wall that doesn't extend all the way to the ceiling. The presence of a phase boundary between liquid and gas is path dependent and can also be determined by dynamic quantities, as shown in the article "Indistinguishable liquid and gas" by Vadim V. Brazhkin and Kostya Trachenko.
  • #1
oxivixo
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Starting from a gas state and reaching the liquid state by getting around the critical point in a p-T phase diagram, what happens (qualitatively) to the molecules (or atoms)? Does a fraction of them start to form bonds?

This concept of "indistinguishable" liquid and gas is new to me.
 
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http://books.google.com/books/about/Lectures_on_Phase_Transitions_and_the_Re.html?id=DdB1__nl7CYC gives the analogy that it's like two rooms, but the wall between them doesn't go all the way to the top. So whether you see "latent heat" associated with a phase transition is path dependent.

Typically, a phase boundary is defined by a discontinuity in some equilibrium thermodynamic quantity. It is by that sort of definition that whether one encounters a phase boundary between liquid and gas is path dependent.

There was however this interesting article in Physics Today about how dynamical quantities can provide an approximate boundary between liquid and gas above the critical point.

http://www.physicstoday.org/resource/1/phtoad/v65/i11/p68_s1?bypassSSO=1
Vadim V. Brazhkin and Kostya Trachenko
 
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What is the state of matter beyond the critical point?

Beyond the critical point, matter exists in a state known as a supercritical fluid. This state is characterized by properties of both a liquid and a gas, and it is often referred to as the fourth state of matter.

What makes the state beyond the critical point different from a liquid or gas?

The state beyond the critical point differs from a liquid or gas due to the absence of a distinct liquid-gas phase boundary. At this point, the properties of the substance change continuously, rather than exhibiting a distinct phase change.

How is the critical point of a substance determined?

The critical point of a substance is determined by its temperature and pressure, at which the liquid-gas phase boundary disappears. This point can also be identified by the sudden change in properties such as density, viscosity, and compressibility.

What are some practical applications of supercritical fluids?

Supercritical fluids have a range of practical applications, including in extraction processes, as a solvent for cleaning and dry-cleaning, and in the production of pharmaceuticals and polymers. They are also used in the development of new materials and in carbon capture and storage technologies.

Can substances exist in a state beyond the critical point in nature?

Yes, substances can exist in a state beyond the critical point in nature. For example, the Earth's core is thought to exist in a supercritical state due to the extreme temperatures and pressures present. Additionally, certain planets and moons in our solar system may have supercritical fluid oceans beneath their surfaces.

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