Find Error in Calculating Energy Eigenstates of Particle in Box

In summary, the conversation discusses a particle of mass m in a box of length L and its energy eigenstates and wave functions. At time t=0, the particle is in a state described by the sum of three phi-terms. In order to find the energy for this state, the Hamiltonian is applied and the energy terms are added up. The error in the calculation is identified and the probability of the system having an energy value of 9E_1 is requested.
  • #1
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I have a particle of mass m in a box of length L. The energy eigenstates of this particle have wave functions
[tex]\phi_{n}(x)=\sqrt{2/L}sin(n \pi x/L)[/tex]
and energies
[tex]E_n = n^{2}\pi^{2}\hbar^{2}/2mL^{2}[/tex]
where n=1, 2, 3,... At time t=0, the particle is in a state described as follows.
[tex]\Psi(t=0)=\frac{1}{\sqrt{14}}[\phi_1 + 2\phi_2 + 3\phi_3][/tex]
To find the energy for state [tex]\Psi[/tex] I did the following.
[tex]\sum_{1, 2, 3} E_n = (1^2 + 2^2 +3^2) \frac{\pi^2\hbar^2}{2mL^2}=14\frac{\pi^2\hbar^2}{2mL^2}= 14E_1 [/tex]
where [tex]E_1=\frac{\pi^2\hbar^2}{2mL^2}[/tex]
I have made a mistake somewhere because the actual answer is [tex]9 E_1[/tex]. Does anyone know where my error is?
 
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  • #2
Well just apply the Hamiltonian onto the state psi. this state is the sum of three phi-terms. So each phi-state yields :
[tex]H \phi_1 = E_1 \phi_1[/tex]
[tex]2H \phi_2 = 2E_2 \phi_2[/tex]
[tex]3H \phi_3 = 3E_3 \phi_3[/tex]

Just add up everything and you get :

[tex]H \Psi =\frac {1}{\sqrt14} (E_1 \phi_1 + 2E_2 \phi_2 + 3E_3 \phi_3)[/tex]

The clue is to write down each energy term as a function of [tex]E_1[/tex]. You have a formula given to do that. Keep in mind that the coefficients of the psi-wave-function denote the possible energy values for the system



Good Luck

marlon
 
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  • #3
Ps, as an additional question : can you give me the probability that the psi-system has energy value 9E_1 ?

regards
marlon
 

What is a particle in a box?

A particle in a box is a simplified model used in quantum mechanics to describe the behavior of a particle confined to a one-dimensional space. In this model, the particle is assumed to be confined within a potential well, with impenetrable walls at either end.

What are energy eigenstates?

Energy eigenstates, also known as stationary states, are quantum states in which a particle has a well-defined energy. In the particle in a box model, the energy eigenstates correspond to the different energy levels that the particle can have while confined within the potential well.

What is the relationship between energy eigenstates and the Schrödinger equation?

The Schrödinger equation is a fundamental equation in quantum mechanics that describes the evolution of a quantum system over time. The energy eigenstates of a particle in a box can be determined by solving the time-independent Schrödinger equation for this specific system.

What is the "error" in calculating energy eigenstates of a particle in a box?

The "error" in calculating energy eigenstates of a particle in a box refers to the difference between the theoretical values predicted by the Schrödinger equation and the actual values obtained through experimental measurements. This error can arise due to various factors such as approximations made in the model, limitations of the measuring equipment, and external influences on the particle.

How can the accuracy of energy eigenstate calculations be improved?

To improve the accuracy of energy eigenstate calculations, more sophisticated mathematical models and techniques can be used, such as the finite difference method or the variational method. Additionally, using higher precision measuring equipment and minimizing external influences on the particle can also help to reduce errors in the calculations.

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