PKa values for weak/strong bases

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In summary, in chemistry, there is a distinction between weak and strong acids, as well as weak and strong bases. However, there is no set limit for the pKa or pKb values that determine whether an acid or base is strong or weak. This can vary based on factors such as the solvent being used, solvation effects, and proton donation or acceptance from the medium. In general, a pKa or pKb value below 1 is considered strong, while above 3 is considered weak, with a grey area in between. However, in different solvents, these values can change and what is considered strong or weak may vary.
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kasse
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In chemistry it's normal to distinguish between weak and strong acids. Is there a limit for the pKa value that determines what is strong and what is weak?

Equivalent, for bases, is there a pKb value that separates weak and strong bases?
 
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As a first approximation you may assume that everything with pKa<1 is strong, and everything with pKa>3 is weak (symmetrically for bases). Between 1 and 3 is a grey area. But if now someone will answer telling you that strong is below 0 and weak is above 2 - s/he will be right as well. There is no set limit, as these things tend to be somewhat relative.
 
  • #3
And of course we mostly think in terms of water solvent. But in liquid ammonia solvent anything stronger than acetic acid is 'strong' and fully dissociated, while in acetic acid solvent HCl and HNO3 are fully associated and perchloric acid is one of the few remaining dissociated, so 'strong'. This is called a 'levelling' effect.

It depends on solvation effects and (not always) oproton donation to /acceptance from the medium.
These effects are absent in the gas phase where all molecules are extremely weak acids. But there e.g. the water molecule is a weaker acid (proton donor) than toluene!
You will mostly deal with water medium but just a little relativisation. :cool:
 

1. What is the definition of pKa value?

The pKa value is a measure of the acid dissociation constant (Ka) of a substance. It is a logarithmic scale that indicates the strength of an acid or base.

2. How do pKa values differ for weak and strong bases?

Strong bases have higher pKa values, indicating a lower strength as an acid. Weak bases have lower pKa values, indicating a higher strength as an acid.

3. How are pKa values determined for bases?

pKa values for bases are determined by measuring the concentration of the conjugate acid and base at equilibrium and using the Henderson-Hasselbalch equation: pKa = -log(Ka) = pH + log([A-]/[HA])

4. What is the relationship between pKa values and pH?

The lower the pKa value, the stronger the acid and the lower the pH. The higher the pKa value, the weaker the acid and the higher the pH. This relationship is described by the Henderson-Hasselbalch equation.

5. How do pKa values affect the strength of a base in a solution?

The pKa value of a base determines its equilibrium in a solution. A lower pKa value indicates a stronger base, meaning it will more readily accept a proton and shift the equilibrium to the right. A higher pKa value indicates a weaker base, meaning it will less readily accept a proton and shift the equilibrium to the left.

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