How Does the Gibbs-Helmholtz Equation Relate to Calculating Enthalpy?

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In summary, the conversation discusses the representation of a formula in the physical world and how to solve for \Delta H. It touches on the topic of entropia, the Gibbs-Helmholtz equation, and its application in chemistry and thermodynamics. The equation \left[\frac{\partial \Delta G}{\partial T}\right]_p = -\Delta S is mentioned, with the suggestion to solve for H by canceling terms and obtaining Enthalpy from a plot of \Delta G/T vs 1/T.
  • #1
neo2478
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Can somebody please shed a little light on what this formula represents in the physical world?
And how could I solve it to get [tex]\Delta H[/tex]?

[tex]
\left[\frac{d\left(\frac{\Delta G}{T}\right)}{\delta T}\right]_p = \frac{\Delta H}{T^2}
[/tex]
 
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  • #2
humm ..looks like entropia. Or may be I'm completely wrong.
 
  • #3
So, you are saying that
[tex]
\left[\frac{d\left(\frac{\Delta G}{T}\right)}{\delta T}\right]_p = \Delta S
[/tex]
?
 
Last edited:
  • #4
no i wrote that, but I'm not saying that :-).
Anyway should be something about Gibbs-Helmholtz equation, but i don't remeber much about it.
So something about chemistry and termodinamics application usually.

[tex]

\left[\frac{\partial \Delta G}{\partial T}\right]_p = -\Delta S

[/tex]

But wait a reply from someone that know of what is talking about because I'm not sure.
 
  • #5
Gibbs Helmholtz
Note d(1/T)/dT is 1/T2. Solve for H. Cancel terms.
So Enthalpy can be obtained from plot of deltaG/T vs 1/T
 

1. What is thermodynamics?

Thermodynamics is a branch of physics that deals with the study of heat, work, and energy, and how they relate to each other in a system.

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The three laws of thermodynamics are: 1. First Law: Energy cannot be created or destroyed, only transferred or converted from one form to another.2. Second Law: The total entropy of a closed system will never decrease over time.3. Third Law: As temperature approaches absolute zero, the entropy of a system also approaches zero.

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