Electron Affinities: Fluorine vs Chlorine & EA Explained

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In summary, the conversation discusses the difference in electron affinity (EA) between fluorine and chlorine, which goes against the trend of EA increasing as you go up and right on the periodic table. It is suggested that this can be explained by the electron configurations of both F- and Cl-, with one being more stable and thus requiring more energy to remove an electron.
  • #1
kay
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Why is the EA of Fluorine higher than chlorine when it shouldn't be according to periodic trends?

And in general when it is easy to add an electron to a substance, then is the EA high or low?
 
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  • #2
I'm sorry you are not finding help at the moment. Is there any additional information you can share with us?
 
  • #3
I forgot to add that by EA i meant 'Electron Affinity.' I think that's all. :(
 
  • #4
Are you referring to electronegativity? The trend is higher as you go up and right on the periodic table, so F being more electronegative than Cl does not defy the trend.

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  • #5
I mean Electron Gain Enthalpy or Electron Affinity.
 
  • #6
So is there no one who knows the answer? :eek:
 
  • #8
I think it can be explained by use of electron configuration of both F- and Cl-; one is more stable than the other. Therefore the energy to remove an electron from it is essentially larger than that of the other.
 

1. What is electron affinity?

Electron affinity is the amount of energy released when an atom gains an electron to form a negative ion. It is the measure of an atom's ability to attract and hold onto additional electrons.

2. What is the difference between fluorine and chlorine's electron affinity?

Fluorine has a higher electron affinity than chlorine. This means that fluorine has a stronger ability to attract and hold onto additional electrons compared to chlorine.

3. How do you explain the difference in electron affinity between fluorine and chlorine?

The difference in electron affinity between fluorine and chlorine can be explained by their atomic structures. Fluorine has a smaller atomic radius and a higher nuclear charge compared to chlorine, making it more electronegative and able to attract electrons more strongly.

4. Why is fluorine's electron affinity higher than chlorine's?

Fluorine's electron affinity is higher than chlorine's because of its position in the periodic table. Fluorine is located in the top right corner of the periodic table, and as you move from left to right, the atomic radius decreases and the nuclear charge increases, resulting in a higher electron affinity.

5. What are some real-world applications of electron affinity?

Electron affinity plays a crucial role in determining the chemical properties of elements and how they react with other elements. It is also used in industries such as battery manufacturing and semiconductor technology to create more efficient and stable materials.

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