Mass spectrum-need 3 peak designations

[FlipStyle1308]

Homework Statement

I am assigning m/z peaks on a mass spectrum, and there are 3 peaks not on the chart given by the instructor, and I was wondering if anyone can help me determined their identities. The peaks I am unsure of are found at 95 m/z, 109 m/z, and 123 m/z; I already figured out the rest of them. Thanks!

Homework Equations

N/A.

The Attempt at a Solution

I already determined the 4 peaks on the left and the 2 on the right, and just need help with the peaks at 95 m/z, 109 m/z, and 123 m/z.

Spectrum found at:

 

[chemisttree]

Looks like the textbook example of bicyclo[n.o.t.]forbiddenene.
I've seen this and a closely related structure, message[4.0.4]failurene, many times in my travels on the internet...

 

[Blueshift5]

Hello,

Thank you for reaching out for help with your mass spectrum assignment. In order to accurately determine the identities of the three unknown peaks at 95 m/z, 109 m/z, and 123 m/z, you may need to provide more information such as the type of sample being analyzed and the method of ionization used. Additionally, the intensity of each peak can also provide valuable information in identifying the compounds present. I would recommend consulting with your instructor or conducting further research on mass spectrometry to determine the identities of these peaks. Best of luck with your assignment!