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Why isn't rotation included when calculating the average energy of a monatomic gas? |
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| Sep14-12, 05:11 PM | #1 |
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Why isn't rotation included when calculating the average energy of a monatomic gas?
Greetings, this is my first post, though I have been reading these forums for a while.
I understand that the average energy of each degree of freedom in a thermodynamic system in equilibrium is kT/2. My textbook says that for a monatomic gas particle, the only degrees of freedom that count are movement in three dimensional space, so the average energy of such a particle is 3kT/2. My question is, why don't rotations contribute toward the average energy? My textbook suggests that this is because the moment of inertia is vanishingly small. However, my thought is that if the moment of inertia is very small, it just means that the particle would be spinning extremely fast in order to reach an average energy of kT/2 for each rotational axis. sanbyakuman |
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| Sep14-12, 05:45 PM | #2 |
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Your description is one of classical physics. You are correct: rotational energy may be significant.
Try these sections in this link: http://en.wikipedia.org/wiki/Heat_ca...ees_of_freedom The effect of quantum energy levels in storing energy in degrees of freedom Energy storage mode "freeze-out" temperatures |
| Sep14-12, 07:34 PM | #3 |
Recognitions:
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Making an unsymmetrical object like a diatomic molecule spin isn't a problem. All you have to do is hit one end of it in a collusion, for example. |
| Sep14-12, 09:28 PM | #4 |
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Why isn't rotation included when calculating the average energy of a monatomic gas? |
| Sep14-12, 11:15 PM | #5 |
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single atoms are considered to not be able to rotate. this is taught in basic statistical mechanics. there are electronic degrees of freedom but they require such high temperature to excite for most molecules that they don't play a major role.
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| Sep15-12, 10:13 AM | #6 |
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Thanks everyone for your replies. I understand now.
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