New Reply

1st law of thermodynamics and statevariables

 
Share Thread
Sep12-12, 08:49 AM   #1
 

1st law of thermodynamics and statevariables


Hello,

My book gives the equation du=Tds-pdV as for the first law of thermodyanmics. The book derives this for a reversible process, but then makes the comment that u,p,V,T,s are all states variables, therefore this equation is valid for any irreversible processes as well. What confuses me is that I accept the fact that those variables are all state variables, but pdV is work which is not a state variable. So, how can this equation be valid for an irreversible process?

Thank you very much
PhysOrg.com physics news on PhysOrg.com

>> Cheap, color, holographic video: Better holographic video displays
>> First entanglement between light and optical atomic coherence
>> EUROnu project recommends building Neutrino Factory
New Reply

Similar discussions for: 1st law of thermodynamics and statevariables
Thread Forum Replies
Thermodynamics- Zemansky Heat and Thermodynamics book question Advanced Physics Homework 0
Thermodynamics and Statistical Thermodynamics References Science Textbook Discussion 9
Physical Chemistry books (Thermodynamics/Statistical Thermodynamics/Kinetics/QM) Science Textbook Discussion 1
Thermodynamics: violation of 1st and/or 2nd law of thermodynamics in a heat engine Introductory Physics Homework 7
Prof teaches Statistical thermodynamics in a Classical Thermodynamics class Academic Guidance 10