Pickling of steel in Hydrochloric Acid

In summary, the conversation discusses various methods for removing rust from mild steel pipes. It is noted that immersing a test sample in 15% hydrochloric acid for 4 hours effectively removes rust from the surface, but subsequent attempts on a larger scale result in rapid corrosion due to chlorine remaining on the steel surface. The conversation also mentions an alternative method of using molasses for a slower rust removal process, as well as commercial rust converters that protect the surface with a phosphate. The cause of the rapid corrosion is determined to be the presence of chlorine on the steel surface.
  • #1
selseg
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I have some pieces of rusted mild steel pipes that i intend to remove rust from.I inserted a test sample in 15% Hydrochloric acid for 4 hours after which all the rust was removed from the surface and corrosion has slowed dramatically after washing off the acid.The subsequent pieces of steel pipe I tried on a large scale showed rapid corrosion soon after the pipes have been removed from the acid .What could be the cause of this
 
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  • #2
Chlorine from the HCl remains on the steel surface and causes corrosion to return. Once an iron surface is poisoned with chlorine it is close to impossible to remove. It is a real problem in marine situations and causes car bodies to rust where salt is used on the road to prevent ice.

A slower process, that is often preferred by tool and machinery re-builders, is to immerse a rusty item in molasses for a week.
http://www.practicalmachinist.com/vb/general-archive/rust-removal-using-molasses-90452/

There are commercial rust converters that protect the surface with a phosphate.
 

1. What is the purpose of pickling steel in hydrochloric acid?

The purpose of pickling steel in hydrochloric acid is to remove impurities and surface oxides from the steel. This process helps to improve the appearance and quality of the steel, as well as prepare it for further processing or use.

2. How does hydrochloric acid pickle steel?

Hydrochloric acid pickling involves immersing the steel in a dilute solution of hydrochloric acid. The acid reacts with the surface oxides and impurities on the steel, dissolving them and creating a clean surface. The acid also helps to neutralize any alkaline residues on the steel, preventing future corrosion.

3. What are the benefits of pickling steel in hydrochloric acid?

Pickling steel in hydrochloric acid has several benefits, including removing surface contaminants and impurities, improving the appearance and finish of the steel, and preparing it for further processing such as welding, plating, or painting. It also helps to prevent corrosion and improve the overall quality and durability of the steel.

4. What safety precautions should be taken when pickling steel in hydrochloric acid?

When pickling steel in hydrochloric acid, it is important to wear proper protective gear such as gloves, goggles, and a respirator to avoid contact with the acid. The acid should also be handled and stored in a well-ventilated area, and any spills should be cleaned up immediately. It is also important to follow the appropriate dilution and disposal guidelines for the acid.

5. Can other acids be used to pickle steel besides hydrochloric acid?

Yes, other acids such as sulfuric acid or nitric acid can also be used for pickling steel. Each acid may have different effects on the steel's surface and may require different safety precautions. It is important to consult with a professional or follow the manufacturer's instructions when using alternative acids for pickling steel.

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