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Paramagnetism of Free Ions. Sign problem.

by LagrangeEuler
Tags: free, ions, paramagnetism, sign
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Sep1-13, 11:10 AM
P: 316
Energy of system of magnetic dipoles is
##E_H=-\mu_0 \vec{\mu}\cdot \vec{H}=-\mu_0\mu_zH##
why sign ''-''?
and ##\mu_z=-g_J\mu_Bm##
Again why ''-'' sign ?
##z## is choosen to be quantization direction, and along that direction is applied field ##H##.
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Sep2-13, 11:22 AM
P: 34
E=m[itex]\bullet[/itex]B but as the material has a magnetization M and B= H+M then H must face the opposite direction to B and that explains the first negative sign I think.
M Quack
Sep17-13, 03:27 PM
P: 667
In a paramagnet, the magnetization of the material is parallel to the applied field. In a diamagnet it would be antiparallel (opposite).

The first "-" is there because the energy decreases when a magnetic moment is parallel to the applied field.

The second "-" does not make any sense to me.

H appears to be along the positive z direction. Then the magnetization mu_z should also be along the positive z direction, and it should be proportional to H. The magnitude of the magnetization also depends on the temperature.

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