Phosphorus with 5 covalent bonds

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In summary, phosphorus can have more than 4 covalent bonds, specifically in the quantum level number 3 where the 3s orbital is full, 3p orbital is half filled, and 3d orbital is vacant and energetically accessible. This results in pentavalent P chemistry, which is important in biological compounds such as DNA, RNA, and ATP.
  • #1
amolv06
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My o-chem book says that phosphorus can have more than 4 covalent bonds. Why is this with respect to valence bond theory?
 
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  • #2
I'd guess hybridization of the d orbital, but I haven't really much experience with chemistry.
 
  • #3
consider the quantum level number 3 of phosphorous.

3s is full, 3p is half filled and 3d is vacant and energetically accessible.

in what way can you get 5 covalent bonds?
 
  • #4
amolv06 said:
My o-chem book says that phosphorus can have more than 4 covalent bonds.

You are saying this like it's a surprise but the most important and ornery P chemistry is pentavalent, esp. bio., all the most important compounds like DNA RNA ATP comes into nearly everything.
 

1. What is phosphorus with 5 covalent bonds?

Phosphorus with 5 covalent bonds refers to a type of phosphorus atom that is bonded to five other atoms through covalent bonds. Covalent bonds are formed when atoms share electrons in order to attain a stable outer electron shell.

2. How is phosphorus with 5 covalent bonds different from regular phosphorus?

Regular phosphorus usually forms three covalent bonds, but in some cases, it can form five covalent bonds. This results in a different molecular structure and properties for phosphorus with 5 covalent bonds compared to regular phosphorus.

3. What are the properties of phosphorus with 5 covalent bonds?

Phosphorus with 5 covalent bonds is typically more reactive and unstable compared to regular phosphorus. It can also exhibit different physical and chemical properties, depending on the atoms it is bonded to.

4. What are some examples of molecules containing phosphorus with 5 covalent bonds?

Some examples of molecules containing phosphorus with 5 covalent bonds include phosphorus pentachloride (PCl5), phosphorus pentafluoride (PF5), and phosphorus pentoxide (P2O5).

5. How is phosphorus with 5 covalent bonds used in scientific research and industries?

Phosphorus with 5 covalent bonds is commonly used as a reagent in chemical reactions and synthesis processes. It is also utilized in the production of fertilizers and in the manufacturing of electronic components such as transistors and semiconductors.

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