Shift Equilibrium: 2NOBr -> 2NO + Br2 - Which Option?

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In summary, shift equilibrium refers to the process of adjusting the balance between reactants and products in a chemical reaction to reach a state of equilibrium. The equation for this shift equilibrium can be seen in the reaction 2NOBr ⇌ 2NO + Br2, and it occurs because the reaction is reversible. The shift equilibrium can be shifted towards the products by altering temperature, pressure, or concentrations. Its significance lies in allowing for dynamic equilibrium and balance between reactants and products in chemical processes.
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Soaring Crane
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The decomposition of nitrosyl bromide is exothermic: 2NOBr (g) <-> 2NO (g) + Br2 (g). Which of the following changes in reaction condition will shift the reaction to the left?


a. add more NOBr

b. decrease the temperature

c. increase the container volume

d. none of these

Is this right? Thanks.
 
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Yep, it's right.
 
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Option b. decrease the temperature will shift the reaction to the left. According to Le Chatelier's principle, decreasing the temperature of an exothermic reaction will favor the reactants, in this case, 2NOBr. This is because decreasing the temperature decreases the kinetic energy of the molecules, making it more difficult for them to overcome the activation energy barrier and form products. Therefore, the equilibrium will shift to the left in order to counteract this change and maintain a state of equilibrium. Adding more NOBr or increasing the container volume would not have a significant effect on the equilibrium since they do not directly affect the temperature of the reaction.
 

1. What is shift equilibrium?

Shift equilibrium refers to the process of adjusting the balance between reactants and products in a chemical reaction in order to reach a state of equilibrium. This can involve changes in temperature, pressure, or concentrations of the reactants and products.

2. What is the equation for the shift equilibrium of 2NOBr to 2NO + Br2?

The equation for the shift equilibrium of 2NOBr to 2NO + Br2 is: 2NOBr ⇌ 2NO + Br2

3. Why does the shift equilibrium occur in this reaction?

The shift equilibrium occurs in this reaction because it is an example of a reversible reaction, meaning that the products can react with each other to form the original reactants. As a result, the system will constantly shift between the forward and reverse reactions until reaching a state of equilibrium.

4. How can the shift equilibrium be shifted towards the products?

The shift equilibrium can be shifted towards the products by increasing the concentration of the reactants, decreasing the concentration of the products, increasing the temperature, or decreasing the pressure. This will cause the reaction to favor the forward reaction in order to reach a new state of equilibrium.

5. What is the significance of the shift equilibrium in terms of chemical reactions?

The shift equilibrium is significant in chemical reactions because it allows for dynamic equilibrium, where both the forward and reverse reactions are still occurring but at equal rates. This allows for a balance between reactants and products, which is essential for many chemical processes to occur in living organisms and industrial processes.

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