What is the correct IUPAC name for compound (b) with a chiral center on C2?

In summary, the correct systematic name for compound (a) is N-phenylhydroxylamine and for compound (b) it is 1,1-dichloro-2-ethylcycloheptane. However, it should be noted that compound (b) has a chiral center on C2, which will affect its IUPAC name depending on the location of the ethyl group (R or S).
  • #1
KLscilevothma
322
0
Which one is the correct systematic name for compund (a), N-hydroxyaniline or N-phenylhydroxylamine ?

Also, how should we name compound (b), 2,2-dichloro-1-ethylcycloheptane or 1,1-dichloro-2-ethylcycloheptane ?

http://www.angelfire.com/alt2/antiwork
 
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  • #2
umm can you show the structure for a and b? haven't done nomenclature in awhile, but i should be able to figure it out pretty quick.
 
  • #3
nevermind, had a brain fart.

i believe (a) is N-phenylhydroxylamine

and (b) is 1,1-dichloro-2-ethylcycloheptane
 
  • #4
Thanks
 
  • #5
no problem. however i should point out that (b) has a chiral center on C2, this will change it's IUPAC name depending on where the ethyl group is located (R or S).
 

1. What is nomenclature?

Nomenclature is the system of naming chemical compounds in a standardized manner, using rules set by the International Union of Pure and Applied Chemistry (IUPAC).

2. Why is nomenclature important in chemistry?

Nomenclature is important because it allows scientists to communicate and identify chemical compounds accurately and unambiguously. This is crucial in research, education, and industry.

3. What are the basic rules of IUPAC nomenclature?

The basic rules of IUPAC nomenclature include:

  • Compounds are named based on their molecular structure and functional groups.
  • The longest carbon chain in the molecule is used as the base name.
  • Suffixes and prefixes are added to indicate the type and position of functional groups.
  • Numerical prefixes (such as di-, tri-, tetra-) are used to indicate the number of identical substituents.
  • Hydrogen atoms attached to carbon in the main chain are not explicitly named.

4. Are there exceptions to the rules of IUPAC nomenclature?

Yes, there are some exceptions to the rules of IUPAC nomenclature. For example, common names may be used for some compounds that are well-established and widely used, such as water (H2O) and ammonia (NH3). Also, certain functional groups may have special names, such as carboxylic acid (-COOH) and aldehyde (-CHO).

5. How does IUPAC nomenclature apply to stereoisomers?

IUPAC nomenclature provides a specific set of rules for naming stereoisomers, which are compounds with the same molecular formula and connectivity but different spatial arrangements. The system uses prefixes such as cis- and trans- for geometric isomers, and R- and S- for chiral molecules. It also takes into account the relative positions of substituents on a ring structure in cyclic compounds.

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