Why is the direction of the dipole moment always taken from -q to +q?

In summary, the convention for the direction of the dipole moment of an electric dipole is from -q to +q, which may seem contradictory when drawing electric lines of force. However, this convention is based on the natural definition of dipole moment as the first moment of the charge distribution, where the resulting vector points from -q to +q. This is also consistent with the stable equilibrium position of a dipole in an electric field, where the dipole moment is parallel to the electric field.
  • #1
ananthu
106
1

Homework Statement



Can anyone explain why the direction of the dipole moment of an electric dipole is always taken as "from -q to +q" but not "from +q to -q"? In fact when we draw the electric lines of force we are only drawing in such a way that they start from +q and terminate at -q.Then why this contradiction? What is the correct explanation for this convention?

Homework Equations





The Attempt at a Solution

 
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  • #2
ananthu said:
Can anyone explain why the direction of the dipole moment of an electric dipole is always taken as "from -q to +q" but not "from +q to -q"?
It's just a convention.
In fact when we draw the electric lines of force we are only drawing in such a way that they start from +q and terminate at -q.Then why this contradiction?
What does that have to do with the definition of dipole moment? There's no contradiction.
 
  • #3
But why is the convention for a dipole the opposite to the other convention? :confused:
 
  • #4
tiny-tim said:
But why is the convention for a dipole the opposite to the other convention? :confused:
Ah... now I understand the question. The "natural" definition of dipole moment (the first moment of the charge distribution) is:

[tex]\vec{p} = q_1\vec{r}_1 + q_2\vec{r}_2[/tex]

That will give the direction of the dipole moment as minus to plus.
 
  • #5
When you keep a dipole in an electric field, it acquires the stable equilibrium position with positive charge toward the electric field. Potential energy for a dipole is given by
U = - p.E
It has minimum value = -pE at the stable equilibrium position. It is possible only when p is parallel to E, i.e. p is from -q to +q.
 
  • #6
rl.bhat said:
When you keep a dipole in an electric field, it acquires the stable equilibrium position with positive charge toward the electric field. Potential energy for a dipole is given by
U = - p.E
It has minimum value = -pE at the stable equilibrium position. It is possible only when p is parallel to E, i.e. p is from -q to +q.
But if you defined the dipole moment with the opposite convention, U = p.E. And the minimum value would be when p is anti-parallel to E. The physics wouldn't change. (Not that I'm suggesting one flout convention. :wink:)
 
  • #7
Doc Al said:
Ah... now I understand the question. The "natural" definition of dipole moment (the first moment of the charge distribution) is:

[tex]\vec{p} = q_1\vec{r}_1 + q_2\vec{r}_2[/tex]

That will give the direction of the dipole moment as minus to plus.

Will you please elaborate this point?
 
  • #8
ananthu said:
Will you please elaborate this point?
I'll try. Let q1 = +q and q2 = -q, then:

[tex]\vec{p} = q_1\vec{r}_1 + q_2\vec{r}_2 = q\vec{r}_1 - q\vec{r}_2 = q(\vec{r}_1 - \vec{r}_2)[/tex]

The vectors r1 and r2 are the position vectors of +q and -q. Thus the vector r1 - r2 points from -q to +q.
 
  • #9
Doc Al said:
I'll try. Let q1 = +q and q2 = -q, then:

[tex]\vec{p} = q_1\vec{r}_1 + q_2\vec{r}_2 = q\vec{r}_1 - q\vec{r}_2 = q(\vec{r}_1 - \vec{r}_2)[/tex]

The vectors r1 and r2 are the position vectors of +q and -q. Thus the vector r1 - r2 points from -q to +q.

Thank you. Now it is clear.
 

What is a dipole moment?

A dipole moment is a measure of the separation of positive and negative charges in a molecule. It is a vector quantity, with both magnitude and direction, and is usually represented by an arrow pointing from the negative to the positive end.

How is the direction of a dipole moment determined?

The direction of a dipole moment is determined by the electronegativities of the atoms involved in the bond. The more electronegative atom will have a slightly negative charge, while the less electronegative atom will have a slightly positive charge. The direction of the dipole moment will point towards the more electronegative atom.

What factors affect the magnitude of a dipole moment?

The magnitude of a dipole moment is affected by the difference in electronegativities between the atoms involved in the bond, as well as the distance between the charges. The larger the difference in electronegativities and the shorter the distance between the charges, the greater the magnitude of the dipole moment.

Can a molecule have more than one dipole moment?

Yes, a molecule can have multiple dipole moments if it contains more than one polar bond. In this case, the individual dipole moments will combine to give an overall dipole moment for the molecule.

How is the direction of a dipole moment represented in a molecule?

The direction of a dipole moment is represented by an arrow pointing from the negative to the positive end of the molecule. This arrow is often shown in structural diagrams of molecules to indicate the polarity of the bonds and the overall polarity of the molecule.

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