Mass Spectrometry Homework: Determining Atomic Mass

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In summary, natural carbon has two isotopes with different masses due to different numbers of neutrons, but the same number of protons and chemical properties. When placed in a mass spectrometer, the more abundant isotope moves in a circle with radius 9.00 cm and the rarer isotope moves in a circle with radius 9.36 cm. Using the equation r = mv^2 / qvB, we can set up a ratio to find the atomic mass of the rarer isotope, which is 12.48 u. However, this answer may be incorrect due to the fact that the ions are accelerated through the same potential difference before entering the magnetic field.
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azhoops
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Homework Statement



Natural carbon consists of two different isotopes (excluding 14C, which is present in only trace amounts). The isotopes have different masses, which is due to different numbers of neutrons in the nucleus; however, the number of protons in the same, and subsequently the chemical properties are the same. The most abundant isotope has an atomic mass of 12.0000 u. When natural carbon is placed in a mass spectrometer, two lines are formed on the photographic plate. The lines show that the more abundant isotope moved in a circle of radius 9.00 cm, while the rarer isotope moved in a circle of radius 9.36 cm. What is the atomic mass of the rarer isotope? (The ions are accelerated through the same potential difference before entering the magnetic field.)

Homework Equations



r = mv^2 / qvB

The Attempt at a Solution



Charges, velocities, and magnetic fields are the same. Set up ratio:

radius abundant / radius rarer = mass abundant / mass rarer

9 cm / 9.36 cm = 12 u / x

x = 12.48 u

This answer shows as incorrect. Any thoughts? Thanks.
 
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  • #2
azhoops said:

Homework Statement


(The ions are accelerated through the same potential difference before entering the magnetic field.)

If they are accelerated through the same potential difference they don't have the same velocity.
 
  • #3
Thanks! I got it.
 

1. What is mass spectrometry?

Mass spectrometry is an analytical technique used to determine the mass of a sample by ionizing it and separating the ions based on their mass-to-charge ratio. This allows scientists to identify the different components of a sample and determine their relative abundance.

2. How is atomic mass determined using mass spectrometry?

In mass spectrometry, the ions are accelerated and separated according to their mass-to-charge ratio. The resulting mass spectrum shows the different masses of the ions present in the sample. By comparing the relative intensities of the peaks in the spectrum, the atomic mass of the element can be determined.

3. What is the significance of isotopes in mass spectrometry?

Isotopes are atoms of the same element that have different numbers of neutrons, resulting in different atomic masses. In mass spectrometry, the presence of isotopes can be detected and their abundance can be measured, providing valuable information about the composition of a sample.

4. Can mass spectrometry be used to identify unknown elements?

Yes, mass spectrometry can be used to identify unknown elements by comparing the mass spectrum of the unknown sample to known spectra of elements. This can help determine the atomic mass and composition of the unknown element.

5. What are some applications of mass spectrometry in scientific research?

Mass spectrometry has a wide range of applications in scientific research, including drug discovery, environmental analysis, and proteomics. It is also used in forensic science, food analysis, and identifying impurities in materials.

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