Electric Field Forces in a Hydrogen Molecule

In summary, the protons must be located opposite each other at a radius r from the center of the sphere in order for the force on each of them to be zero, as the fields due to the electrons and protons will cancel each other out. This problem is a simplified model of a hydrogen molecule, with the magic of quantum mechanics explaining how the electron cloud stays stable around the protons. The solution involves using Gauss's Law and understanding the radial nature of the fields.
  • #1
asiangrrl
15
0
Well, I did the problem. The problem is I KNOW my answer is wrong. Anybody have any idea why? (This is what I've worked out with my friend).

Homework Statement



Imagine a sphere of radius a filled with negative charge of uniform density, the total charge being equivalent to that of two electrons. Imbed in this jelly of negative charge two protons and assume that in spite of their presence the negative charge distribution remains uniform. Where must the protons be located so that the force on each of them is zero? (This is a surprisingly realistic caricature of a hydrogen molecule; the magic that keeps the electron cloud in the molecule from collapsing around the protons is explained by quantum mechanics!)

[Ahhhh logically when I try to think about this, I don't understand how there's ANY way there could be zero force on the protons in a sphere of negative electric charge. But that's non-mathematical.]

Homework Equations



Gauss's Law (sphere)
[tex] E = \frac{Q}{r^2} [/tex]
q = e (charge of an electron)
a = radius of sphere
r = radius of Gaussian sphere

The Attempt at a Solution



So, supposedly, I'm supposed to take a Gaussian surface/sphere within the sphere on which the charges will rest.

The charge density of the sphere is
[tex]\frac{-2q}{\frac{4}{3}\pi a^3}[/tex]
or [tex]\frac{-3q}{2\pi a^3}[/tex].

Therefore the charge on my Gaussian sphere is the charge density times the volume of the Gaussian sphere, or
[tex](\frac{-3q}{2\pi a^3})(\frac{4}{3}\pi r^3)[/tex]
[tex]=\frac{2qr^3}{a^3}[/tex]

[tex]E = q_total/r^2[/tex]
Total charge is 2 electrons - charge inside Gaussian sphere
[tex]q_{total} = 2q - \frac{2qr^3}{a^3}[/tex]
[tex]E = \frac{1}{r^2}(2q - \frac{2qr^3}{a^3}[/tex]
[tex]E = \frac{2q}{r^2} - \frac{2qr}{a^3}[/tex]

When the E field is equal to zero, there is no force.

[tex]0 = \frac{2q}{r^2} - \frac{2qr}{a^3}[/tex]
[tex] \frac{2q}{r^2} = \frac{2qr}{a^3} [/tex]
[tex]r^3 = a^3[/tex]
[tex]r = a[/tex]

The more I look at this the more it doesn't make sense, but I can't pinpoint where the "wrong" is.
 
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  • #2
asiangrrl said:
Well, I did the problem. The problem is I KNOW my answer is wrong. Anybody have any idea why? (This is what I've worked out with my friend).

Homework Statement



Imagine a sphere of radius a filled with negative charge of uniform density, the total charge being equivalent to that of two electrons. Imbed in this jelly of negative charge two protons and assume that in spite of their presence the negative charge distribution remains uniform. Where must the protons be located so that the force on each of them is zero? (This is a surprisingly realistic caricature of a hydrogen molecule; the magic that keeps the electron cloud in the molecule from collapsing around the protons is explained by quantum mechanics!)

[Ahhhh logically when I try to think about this, I don't understand how there's ANY way there could be zero force on the protons in a sphere of negative electric charge. But that's non-mathematical.]

Homework Equations



Gauss's Law (sphere)
[tex] E = \frac{Q}{r^2} [/tex]
q = e (charge of an electron)
a = radius of sphere
r = radius of Gaussian sphere

The Attempt at a Solution



So, supposedly, I'm supposed to take a Gaussian surface/sphere within the sphere on which the charges will rest.

The charge density of the sphere is
[tex]\frac{-2q}{\frac{4}{3}\pi a^3}[/tex]
or [tex]\frac{-3q}{2\pi a^3}[/tex].

Therefore the charge on my Gaussian sphere is the charge density times the volume of the Gaussian sphere, or
[tex](\frac{-3q}{2\pi a^3})(\frac{4}{3}\pi r^3)[/tex]
[tex]=\frac{2qr^3}{a^3}[/tex]

so far this looks good. seems like you forgot a minus sign at the end.

[tex]E = q_total/r^2[/tex]
Total charge is 2 electrons - charge inside Gaussian sphere
[tex]q_{total} = 2q - \frac{2qr^3}{a^3}[/tex]
[tex]E = \frac{1}{r^2}(2q - \frac{2qr^3}{a^3}[/tex]
[tex]E = \frac{2q}{r^2} - \frac{2qr}{a^3}[/tex]

I don't understand why you did this. The field is the total "enclosed charge" divided by r^2... why are you taking 2q and subtracting...

Find the field due to the electrons... taking the above into account.

Now we know that the field due to the electrons is in the radial direction... so the only way that the protons can be placed in the field motionless, if the field that the proton creates a field in the radial direction...

how must the protons be placed to cancel the field due to the electrons?
 
  • #3
correction: So is the field due to the electrons with just [tex]E = (-\frac{2qr^3}{a^2})(\frac{1}{r^2}) = -\frac{2qr}{a^3}[/tex]

I really have no idea how the protons can cancel the electrons unless they were at the same point? Is there any other hint you could give? Thanks again :(
 
Last edited:
  • #4
asiangrrl said:
correction: So is the field due to the electrons with just [tex]E = (-\frac{2qr^3}{a^2})(\frac{1}{r^2}) = -\frac{2qr}{a^3}[/tex]

I really have no idea how the protons can cancel the electrons unless they were at the same point? Is there any other hint you could give? Thanks again :(

Since the field due to the electrons acts radially... the field due to the protons needs to act radially too...

The protons have to be located opposite each other. ie both protons are located at a radius r from the center opposite each other...

So what's the field at one of the protons? You've got the field due to the electrons + the field due to the other proton. The 2 need to add to zero...
 
  • #5
Hmm, I think I am starting to see it. Since the proton will be on the Gaussian sphere at radius r away, for a proton [tex]E = \frac{q}{r^2}[/tex].

So
[tex]E = -\frac{2qr}{a^3} + \frac{q}{r^2} = 0[/tex]?
 
  • #6
asiangrrl said:
Hmm, I think I am starting to see it. Since the proton will be on the Gaussian sphere at radius r away, for a proton [tex]E = \frac{q}{r^2}[/tex].

So
[tex]E = -\frac{2qr}{a^3} + \frac{q}{r^2} = 0[/tex]?

yes, except the field due to the proton will be:

[tex]E = \frac{q}{(2r)^2}[/tex]

so set:

[tex]E = -\frac{2qr}{a^3} + \frac{q}{(2r)^2} = 0[/tex][/QUOTE]
 
  • #7
Ah, 2r since it's a diameter away. Thank you so, so much. I think I understand this now. Yay for starting to get E&M :).
 
  • #8
asiangrrl said:
Ah, 2r since it's a diameter away. Thank you so, so much. I think I understand this now. Yay for starting to get E&M :).

:) no prob.
 

1. What is an electric field force in a hydrogen molecule?

An electric field force in a hydrogen molecule is a force that exists between the positively charged nucleus and the negatively charged electron. It is responsible for holding the atom together and determining its structure.

2. How is the strength of the electric field force in a hydrogen molecule determined?

The strength of the electric field force in a hydrogen molecule is determined by the distance between the nucleus and the electron, as well as the charges of the particles. The force is directly proportional to the charges and inversely proportional to the distance.

3. How does the electric field force affect the energy levels of a hydrogen molecule?

The electric field force affects the energy levels of a hydrogen molecule by causing the electron to move closer or farther away from the nucleus, thus changing its potential energy. This results in different energy levels or orbitals for the electron to occupy.

4. How does an external electric field affect a hydrogen molecule?

An external electric field can affect a hydrogen molecule by altering the balance of the electric field forces between the nucleus and the electron. This can cause the electron to transition to a higher or lower energy level, changing the overall energy and stability of the molecule.

5. Can the electric field force in a hydrogen molecule be manipulated?

Yes, the electric field force in a hydrogen molecule can be manipulated by changing the charges of the particles or altering the distance between them. This can be done through processes such as ionization or by applying external electric fields.

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