Sulfur in Fertiliser: Why the % Mass of Sulfate?

  • Thread starter Stroodle
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In summary, fertiliser producers refer to "the percentage by mass of sulfur present as sulfate" in their fertilisers because sulfur is typically present in the form of sulfates, which are more stable and soluble in water compared to elemental sulfur and sulfites. However, if the fertilizer is time-released, it may also contain zero valent sulfur or sulfur-containing polymers. Similar to sulfur, phosphorous is listed as P2O5 for convenience, but all of it is eventually converted to orthophosphate for uptake by plants.
  • #1
Stroodle
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Hi,

I'd just like to know why fertiliser producers refer to "the percentage by mass of sulfur present as sulfate" in their fertilisers?

Thanks!
 
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  • #2
Because sulfur in fertilizers is typically present in the form of sulfates ... I'll guess that's because elemental sulfur is not soluble in water, and sulfites are too unstable.
 
  • #3
It's possible that it is indeed present as sulfate but if it is time-released, it is usually present as zero valent sulfur or as a sulfur-containing polymer and perhaps both. Rather than speciate all the forms of sulfur present, the assay is given as if all were converted to sulfate.
 
  • #4
Phosphorous is listed as P2O5 though and clearly this is not the active form taken up by plants. I guess it's just a convenient metric, although for the chemist it makes things more complicated.
 
  • #5
In the case as phosphorous, all of the P is converted to orthophosphate and the result is multiplied by a factor to express it as P2O5. A little more complicated but not by much.
 

1. What is sulfur, and why is it important in fertilizers?

Sulfur is a chemical element that is essential for plant growth. It plays a crucial role in the formation of proteins and enzymes, as well as the production of chlorophyll. Sulfur also helps plants absorb other important nutrients, such as nitrogen and phosphorus.

2. How is the percentage mass of sulfate in fertilizer determined?

The percentage mass of sulfate in fertilizer is determined by analyzing the chemical composition of the fertilizer. This is typically done through laboratory testing, where the amount of sulfate present in the fertilizer is measured and calculated as a percentage of the total mass.

3. What is the ideal percentage of sulfate in fertilizer?

The ideal percentage of sulfate in fertilizer varies depending on the type of crop and soil conditions. In general, most plants require a minimum of 10-20% sulfate in the fertilizer for optimal growth. However, some crops, such as legumes, may require higher levels of sulfate for better nitrogen fixation.

4. Are there any risks associated with using fertilizers with high levels of sulfate?

While sulfur is essential for plant growth, excessive amounts of sulfate in fertilizers can lead to soil acidification. This can negatively affect the pH balance and nutrient availability in the soil, ultimately impacting plant growth. It is important to follow recommended application rates and conduct regular soil testing to avoid over-application of sulfate-containing fertilizers.

5. Can sulfur in fertilizers have an impact on the environment?

Yes, excess sulfur in fertilizers can have negative impacts on the environment. When sulfur is applied in large quantities, it can leach into groundwater and cause pollution. It can also contribute to acid rain, which can harm plants, animals, and aquatic life. Therefore, it is important to use fertilizers with sulfate in a responsible and sustainable manner.

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