Clarification Regarding the conditions for STP

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In summary, there is no universally accepted definition of STP. While Changs defines it as 25 degrees Celsius and 1 atm, Atkins defines it as 25 degrees Celsius and 1 bar. Both units are numerically similar, but the use of bar is recommended as the standard pressure.
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Hello all,

I am currently in possession of two chemistry textbooks, Changs and Atkins, which I believe are both fairly new versions. Changs defines STP at 25 degrees Celsius and 1 atm, and Atkins defines STP at 25 degrees Celsius and 1 bar; I understand that numerically it would not make a huge difference (1 atm=101.3 kpa=almost 100 kpa), but which is technically correct?

Thanks.
 
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There is no one, universally accepted definition of STP. Bar is a recommended pressure for a standard state.
 
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Atmospheres were used for something like 100 years until "they" decided to switch standard pressure to 1 bar. Numerically they are nearly identical, obviously.

Ref: http://goldbook.iupac.org/S05921.html
(Getting a lot of mileage out of IUPAC today :smile:)
 

1. What is STP and why is it important?

STP stands for standard temperature and pressure, which is used as a reference point for scientific experiments and calculations. It is important because it allows for consistency and comparison between different experiments and data sets.

2. What are the standard conditions for STP?

The standard conditions for STP are a temperature of 0°C (273.15 K) and a pressure of 1 atmosphere (101.325 kPa). These conditions are used to define the standard molar volume of a gas.

3. How does STP differ from other reference points?

STP differs from other reference points such as standard ambient temperature and pressure (SATP) in that it specifies a specific temperature of 0°C, whereas SATP uses the average ambient temperature. Additionally, STP uses a pressure of 1 atmosphere, while SATP uses a pressure of 1 bar.

4. Can STP be altered by changing the atmospheric pressure?

No, the standard conditions for STP are defined and cannot be altered. However, the pressure can be adjusted to match the standard conditions if needed for a specific experiment.

5. Are there any exceptions to using STP as a reference point?

Yes, there are exceptions to using STP as a reference point. For example, STP is not applicable for high-altitude experiments where the atmospheric pressure is significantly lower. In these cases, alternative reference points may be used.

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