Why do electron configurations differ for elements with Z<20 and Z>90?

In summary, the electron configuration for Z<20 and Z>90 is different due to the filling of the f subshell in the actinides. The correct notation for orbitals is 1s2s2p3s3p3d4s4p, but it is important to note that the (>3)d orbital is filled before the (>4)s orbital. The reason for this can be explained by the Aufbau principle, which states the order in which orbitals are filled. The source for this information may have been from a lecture on crystal fracture, but it is not explained why the electron configuration is different for Z<20 and Z>90.
  • #1
asdf1
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0
why is the electron configuration different for Z<20 and Z>90?
 
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  • #2
Can you please develop?
 
  • #3
Z<20:
1s<2s<2p<3s<3p<4s<3d<4p
but
Z>90
1s<2s<2p<3s<3p<3d<4s<4p ?
 
  • #4
Well, at 90 the actinides start. They have different electron configuration, but not in the way you say (4s is always ahead of 3d). When moving on to the actinides, the f subshell is being filled.

When doing chemical/physical notation of orbitals it is correct to write

1s2s2p3s3p3d4s4p

aswell as:

1s2s2p3s3p4s3d4p

However, it is important to remember that the (>3)d orbital is filled before the (>4)s orbital.
 
  • #5
is there a reason why that is so?
 
  • #6
Do you mean why the actinides are filling their f sunshell or why 4s is filled before 3d?
 
  • #7
read up on the Aufbau principle
 
  • #8
asdf1 said:
Z<20:
1s<2s<2p<3s<3p<4s<3d<4p
but
Z>90
1s<2s<2p<3s<3p<3d<4s<4p ?
Out of curiosity :

1. Where did you read this ?

2. What does the source say about 20 < z < 90 ?
 
  • #9
well, I'm taking a class called crystal fracture and that came up in the lecture notes, but didn't explain why...
 

1. What is the significance of Z<20 and Z>90 in electron configurations?

Z<20 and Z>90 refer to the atomic number of an element, which determines its placement in the periodic table. Elements with Z<20 have a simpler electron configuration due to their lower number of electrons, while elements with Z>90 have more complex electron configurations.

2. How does the number of electrons affect the electron configuration of an element?

The number of electrons in an element determines the energy levels and sublevels in which they are arranged. Elements with fewer electrons (Z<20) have complete outermost energy levels and therefore have a more stable electron configuration. Elements with more electrons (Z>90) have incomplete outermost energy levels and therefore have a less stable electron configuration.

3. Can elements with Z<20 and Z>90 have similar electron configurations?

Yes, elements with Z<20 and Z>90 can have similar electron configurations. This is because the arrangement of electrons is determined by the number of electrons and their energy levels, not just the atomic number. For example, both carbon (Z=6) and silicon (Z=14) have electron configurations of 1s2 2s2 2p2, even though their atomic numbers are different.

4. How does the electron configuration of an element affect its chemical properties?

The electron configuration of an element determines its reactivity and chemical properties. Elements with full outermost energy levels (such as those with Z<20) are less likely to react with other elements, while elements with incomplete outermost energy levels (such as those with Z>90) are more reactive and likely to form bonds with other elements.

5. Can the electron configuration of an element change?

Yes, the electron configuration of an element can change through various processes such as ionization, where an electron is lost or gained, or through excitation, where an electron is temporarily moved to a higher energy level. However, the number of electrons in the element remains the same, so its placement on the periodic table does not change.

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