Negative potential energy and coulomb force

In summary, the coulomb force between two charges is negative if the charges have opposite signs, indicating an attractive force. A negative force results in a positive rate of change of potential, meaning that as the particles are separated, the potential energy increases and the force remains attractive. The binding energy for an electron around a hydrogen atom is negative because the zero point for potential energy is at infinity, so it takes energy to move the electron away from the nucleus. A negative force does not necessarily mean an attractive force, but rather a force that points towards the opposite charge.
  • #1
learning_phys
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The coulomb force is given by k*q1*q2/r^2 so if there are two charges that have negative signs, then the force would be negative. Having said that, a "negative force" would then signal an attractive force since opposites attract.

F=-dU/dx, so a negative force would result in a "positive potential"

Does this mean a positive potential is attractive and a negative potential is repulsive? I'm not sure why there is a negative sign there. If this is the case, then why is the binding energy for an electron around the hydrogen atom -13.6 eV? The energy here is negatice, but the force is "binding"

I'm confused, any thoughts would be appreciated.
 
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  • #2
The + and - simply mean how the system is bound. For example, the - sign in gravity simply implies that unless one piece of matter is infinitely far from the others, that particle remains bound to the others; however, the gravitational force between matter is naturally attractive and so the gravitational potential energy is naturally bound to values increasing in magnitude below 0J. A + sign implies that the system is not bound, meaning that if 2 charges repel, the electric potential energy draws closer to 0J naturally.
 
  • #3
so how does force play into this? an attractive (negative) force results in a unbounded (positive) potential?
 
  • #4
learning_phys said:
F=-dU/dx, so a negative force would result in a "positive potential"
Not a positive potential necessarily, but a positive rate of change of potential. Meaning: If the force points to the left, then the potential energy increases to the right.
Does this mean a positive potential is attractive and a negative potential is repulsive? I'm not sure why there is a negative sign there.
If, as the particles are separated, the potential energy increases, then the force between them is attractive.
If this is the case, then why is the binding energy for an electron around the hydrogen atom -13.6 eV? The energy here is negatice, but the force is "binding"
Realize that the zero point for potential energy is when the electron is far away from the nucleus. Compared to that point, the ground state electron PE is -13.6 eV. Thus, to move the electron from the atom requires energy to be added. (And thus the force is attractive, since moving the electron further out increases the potential energy.)
 
  • #5
Say we have two equal charges of equal mass and opposite sign. Charge A is -q and charge B is q, with the potential =0 and charge A at rest and charge B has an initial velocity towards A of v. So, as charge A goes towards charge B, then potential energy becomes NEGATIVE since it takes energy to pull them apart... however, this is counteracted by the increaseing kinetic energy... thus the total energy of the system will always be 0.5mv^2 right? (ignoring effects of radiation)
 
  • #6
learning_phys said:
Say we have two equal charges of equal mass and opposite sign. Charge A is -q and charge B is q, with the potential =0 and charge A at rest and charge B has an initial velocity towards A of v. So, as charge A goes towards charge B, then potential energy becomes NEGATIVE since it takes energy to pull them apart... however, this is counteracted by the increaseing kinetic energy... thus the total energy of the system will always be 0.5mv^2 right? (ignoring effects of radiation)
Sure. As the charges get closer their potential energy decreases while their kinetic energy increases. The total energy remains constant.
 
  • #7
and by decrease, you mean "increase negatively" just like how the electron has a potential of -13.6eV

does this mean the electron around the hydrogen atom can never have a positive potential?
 
  • #8
learning_phys said:
and by decrease, you mean "increase negatively" just like how the electron has a potential of -13.6eV
Sure, if you want to express it like that. But realize that it's not the sign of the potential that matters but how it changes.
does this mean the electron around the hydrogen atom can never have a positive potential?
Right. As long as you take the usual convention of electric PE being zero at infinity, the electron in a hydrogen atom can never have a positive potential.
 
  • #9
Doc Al said:
If, as the particles are separated, the potential energy increases, then the force between them is attractive.

If the particles are separated, the potential energy increses, then dU/dx is always positive, thus the force is always negative, then does this mean a negative force is always attractive?


Doc Al said:
Realize that the zero point for potential energy is when the electron is far away from the nucleus. Compared to that point, the ground state electron PE is -13.6 eV. Thus, to move the electron from the atom requires energy to be added. (And thus the force is attractive, since moving the electron further out increases the potential energy.).

In this case, if the electron was moved from -13.6 to infinity, then the change in potential energy is positive, but this makes the force negative... does this mean that a negative force increases a potential (instead of saying a negative force means an attractive force)
 
  • #10
learning_phys said:
If the particles are separated, the potential energy increses, then dU/dx is always positive, thus the force is always negative, then does this mean a negative force is always attractive?
It depends on what you mean by "negative"--that's a sign convention.

Let x represent the separation of particle B with respect to particle A. As x increases, B gets further away. Since dU/dx is positive, the force is negative and thus points in the negative x direction. That means the force on B points towards A, and thus is an attractive force.
In this case, if the electron was moved from -13.6 to infinity, then the change in potential energy is positive, but this makes the force negative... does this mean that a negative force increases a potential (instead of saying a negative force means an attractive force)
Read what I just wrote above and rephrase the question if I missed it.
 
  • #11
the coulomb force is attractive between the two charges, but why is the force that is needed to move charge B away not taken into account?

also, what if we let the charge B move towards charge A, then since the potential is decreasing, dU/dx<0, making the force positive?
 
  • #12
learning_phys said:
the coulomb force is attractive between the two charges, but why is the force that is needed to move charge B away not taken into account?
Not sure what you mean. The force needed to (just) move charge B away is equal and opposite to the Coulomb force. (Assuming charge A is fixed.)

F = -dU/dx gives you the force associated with the potential. Any other force is up to you.
also, what if we let the charge B move towards charge A, then since the potential is decreasing, dU/dx<0, making the force positive?
dU/dx is still > 0. The slope of U, and the associated force, doesn't change just because the charge is moving one way or the other.
 

1. What is negative potential energy?

Negative potential energy is a form of energy that is associated with the position or configuration of an object relative to other objects in a system. It represents the ability of a system to do work on another system due to the attractive forces between the objects.

2. How is negative potential energy related to coulomb force?

Negative potential energy is closely related to coulomb force, which is the attractive or repulsive force between two charged particles. The magnitude of the coulomb force is directly proportional to the negative potential energy between the particles. As the negative potential energy decreases, the coulomb force also decreases.

3. Can negative potential energy exist without coulomb force?

No, negative potential energy cannot exist without coulomb force. The two concepts are closely linked and are dependent on each other. Without the attractive or repulsive forces between charged particles, there would be no negative potential energy present in a system.

4. How is negative potential energy calculated?

Negative potential energy can be calculated using the formula U = kQq/r, where U is the negative potential energy, k is the Coulomb constant, Q and q are the charges of the particles, and r is the distance between them.

5. What is the significance of negative potential energy and coulomb force in chemistry?

Negative potential energy and coulomb force play a crucial role in understanding the behavior of atoms and molecules in chemical reactions. They help explain why certain atoms and molecules are attracted to each other and form bonds, while others repel each other. This understanding is essential in predicting and explaining the properties of different chemical compounds.

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