A problem from crystallography

In summary, the homework problem involves finding the spacing between (1,1,1) planes in a tetragonal lattice with given lattice constants. The solution involves using the basic equation for spacing, d = \frac{a}{\sqrt{h^2+k^2+l^2}}, and finding the shortest reciprocal lattice vector orthogonal to the planes, which can be constructed from the three reciprocal primitive vectors.
  • #1
vrinda mukund
37
0

Homework Statement



In a tetragonal lattice a=b=0.25 nm and c= 0.18nm, deduce the spacing between (1,1,1) planes.

Homework Equations



the basic equation in this case is

$$d=\frac{a}{\sqrt{h^2+k^2+l^2}}$$

The Attempt at a Solution



here in the question we are provided with the h,k,l value. my doubt is how to find lattice constant a. for a tetragonal crystal we are having diffrent values for c and a,b. so the lattice constant will not be the same through out the crystal, rite? how to solve this?
 
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  • #2
Use:
[tex]d = \frac{2\pi}{\left|\vec{G}\right|}[/tex]
Where [itex]\vec{G}[/itex] is just the shortest reciprocal lattice vector orthogonal to that plane.

I suggest first finding the three reciprocal primitive vectors. And then construct the shortest reciprocal lattice vector orthogonal to the (1,1,1) planes from those.
 

1. What is crystallography?

Crystallography is the scientific study of the arrangement and properties of crystals, which are solid materials with a regular repeating pattern of atoms, molecules, or ions.

2. What are the practical applications of crystallography?

Crystallography has many practical applications in various fields such as materials science, geology, chemistry, and biology. It is used to determine the structure and properties of materials, including metals, minerals, and proteins, which can aid in the development of new technologies and medicines.

3. How is crystallography used in drug discovery?

Crystallography is an important tool in drug discovery as it allows scientists to determine the structure of proteins and other molecules involved in disease processes. This information can then be used to design and develop new drugs that can target specific molecules and treat diseases more effectively.

4. What is the difference between X-ray crystallography and electron crystallography?

X-ray crystallography and electron crystallography are both techniques used to determine the structure of crystals, but they use different types of radiation. X-ray crystallography uses X-rays to produce diffraction patterns, while electron crystallography uses a beam of electrons. Each technique has its advantages and limitations, and the choice depends on the type of crystal being studied.

5. Why is crystallography important for understanding the behavior of materials?

Crystallography is important for understanding the behavior of materials because the atomic and molecular structure of a material greatly influences its properties and behavior. By determining the structure of a crystal, scientists can better understand how it will interact with other materials, respond to external stimuli, and potentially predict its properties. This information is crucial for the development of new materials for various applications.

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