How is Gibbs Free Energy Calculated?

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In summary: You can use either ΔG = ΔH – T * ΔS or G_products – G_reactants to calculate the change in Gibbs Free Energy, but the former is more general and applies to any specified temperature. The latter only applies to the temperature at which the G values are calculated. In summary, you can use either method to calculate the change in Gibbs Free Energy, but the first method is more versatile as it can be applied to any temperature.
  • #1
afcwestwarrior
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do i have to use this formula Delta G=delta h- t*delta s

or could i calculate it like i calculate delta h, products - reactants
 
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  • #2
I think you can do either way. Which way is depending on what data you've got in hand
 
  • #3
Calculating the change in the Gibbs Free Energy as,
ΔG = ΔH – T * ΔS
Is a more general way to do it since this will be true for any specified temperature, T.

You could calculate it as,
ΔG = G_products – G_reactants
But this will only be valid for the temperature which your table has its G values calculated in. You might have access to a table of standard G of formation, but this would only be true under standard conditions.
What if you had a non-spontaneous reaction (under standard conditions) and you wanted to find out the temperature you needed to raise it to in order to make it spontaneous? To do this, you would have to calculate it the old fashion way without the Free Energy table.
 
  • #4
Gibbs free energy equation is a thermodynamic equation that is used to calculate the change in the Gibbs free energy of a system. The Gibbs Free Energy equation is written as G=H-TS Where G is the Gibbs Free Energy, H is the enthalpy, T is the absolute temperature and S is the entropy.
 

What is delta G and why is it important in scientific calculations?

Delta G, also known as Gibbs free energy, is a thermodynamic quantity that measures the amount of energy available in a system to do useful work. It is important in scientific calculations because it helps determine whether a chemical reaction is spontaneous or non-spontaneous.

How do you calculate delta G?

Delta G can be calculated using the equation ΔG = ΔH - TΔS, where ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy. In simpler terms, delta G is equal to the difference between the energy absorbed or released during a chemical reaction and the energy lost due to disorder in the system.

What does a positive or negative value of delta G indicate?

A positive value of delta G indicates that the reaction is non-spontaneous and requires energy to occur. A negative value of delta G indicates that the reaction is spontaneous and releases energy.

How does temperature affect delta G?

The value of delta G changes with temperature. As temperature increases, the value of delta G becomes less negative, eventually reaching a point where it becomes positive. This means that at higher temperatures, reactions that were previously spontaneous can become non-spontaneous.

What factors influence the value of delta G?

The value of delta G is influenced by the enthalpy change, entropy change, and temperature of a system. Additionally, the concentration of reactants and products can also affect the value of delta G. Changes in pressure, pH, and catalysts can also impact the value of delta G.

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