Calculate heat released in the reaction

In summary, the given reaction involves substances that can undergo combustion reactions and have specific combustion enthalpies at 300K. The reaction occurs at constant volume and is first order with respect to A. If A reduces to half its initial amount in 69.3 seconds, the heat released when 2*10^-3 mole of A has reacted at 300K is 1800 cal/mol. The initial rate of heat release, with initially 1 mole of A present, is not specified.
  • #1
utkarshakash
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Homework Statement


All the substances involved in the reaction given below can undergo combustion reaction and their combustion enthalpies at 300K are given below,
2A(g)+B(g) ----> 3C(g) + D(g)
Given: ΔH A = -1000cal/mol ΔH B= -2000cal/mol ΔH C=-500 cal/mol ΔH D = -100 cal/mol
If the reaction occurs at constant volume at 300K and the reaction obeys first order with respect to A and if A reduces to half its initial amount in 69.3 sec, then calculate

1) heat released when 2*10-3 mole of A has reacted at 300K(in cal)

2) rate at which heat is released initially, if initially 1mol of A is present.


The Attempt at a Solution



ΔH of rxn = 2400 cal/mol
ΔH = ΔU + Δng RT
Since the reaction occurs at constant volume ΔQ = ΔU
ΔQ = ΔH - Δng RT

Substituting appropriate values , I get ΔQ = 1800 cal/mol. But this is not the correct answer.
 
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  • #2
Where does it ask for ΔQ PER MOLE??
 

What is the formula for calculating heat released in a reaction?

The formula for calculating heat released in a reaction is q = m x c x ΔT, where q is the heat released, m is the mass of the substance, c is the specific heat capacity, and ΔT is the change in temperature.

What is the unit of measurement for heat released in a reaction?

The unit of measurement for heat released in a reaction is usually in Joules (J) or calories (cal). However, it can also be expressed in other units such as kilojoules (kJ) or kilocalories (kcal).

How do you determine the specific heat capacity of a substance?

The specific heat capacity of a substance can be determined by conducting a calorimetry experiment. This involves measuring the mass and initial and final temperatures of a substance as it undergoes a reaction. The specific heat capacity can then be calculated using the formula q = m x c x ΔT.

What are the factors that can affect the heat released in a reaction?

The factors that can affect the heat released in a reaction include the type and amount of reactants, the temperature change, and the presence of a catalyst. The physical state of the reactants and the pressure can also have an impact on the heat released.

Can the heat released in a reaction be negative?

Yes, the heat released in a reaction can be negative. This indicates that the reaction is endothermic, meaning heat is absorbed from the surroundings rather than released. In this case, the value for heat released would be represented as a negative number in the calculation.

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