[Chemistry] Calculation of Pt potential

In summary, the conversation discusses the calculation of the potential of a Pt electrode in a solution containing 0.0263M K2PtCl4 and 0.1492M KCl. The Nernst Equation is used in the attempt to find the answer, but it differs from the given answer in the answer key. The possibility of the oxidation/reduction of K+ ions is also mentioned.
  • #1
jkh4
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Homework Statement



Calculate the potential of a Pt electrode immersed in a solution that is 0.0263M in K2PtCl4 and 0.1492M in KCl.
The answer given in 0.78

Homework Equations



E = Eo - 0.05912/2 * log Q (Nernst Equation)

The Attempt at a Solution



We try looking at the reduction of PtCl4 with oxidation of Cl2, and came out with an answer, but its different from the answer key given.

Maybe there is something with the oxidation/reduction of K?Thanks.
 
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  • #2
And not Pt+2/Pt? This is solution of complexed Pt+2, it must contain some free Pt+2. Not much, but that's where I would start.
 
  • #3


I would like to suggest double-checking the calculations and units used in the attempt at the solution. It is important to ensure that all values are in the correct units and that the Nernst equation is applied correctly. Additionally, it may be helpful to consider the standard reduction potential of Pt and K ions in the solution, as well as the activities of the species involved. It is also possible that the given answer may have been rounded or approximated, so it is important to consider the level of precision needed for the calculation. I would also recommend checking for any errors in the given answer key or seeking clarification from the instructor.
 

1. What is Pt potential?

Pt potential is the potential difference between a platinum electrode and a reference electrode, measured in volts. It is a measure of the reactivity or activity of the platinum electrode in a chemical system.

2. How is Pt potential calculated?

Pt potential is calculated using the Nernst equation, which takes into account the concentration of reactants and products, the temperature, and the number of electrons involved in the reaction. The equation is E = E° - (RT/nF)lnQ, where E is the measured potential, E° is the standard potential, R is the gas constant, T is the temperature, n is the number of electrons, F is Faraday's constant, and Q is the reaction quotient.

3. What is the significance of Pt potential in chemistry?

Pt potential is important in determining the thermodynamics and kinetics of a chemical reaction. It can also be used to predict the direction of a reaction and the feasibility of a reaction under certain conditions.

4. How does Pt potential vary with pH?

Pt potential is affected by pH because it can change the concentration of reactants and products in a chemical system. As pH increases, the concentration of H+ ions decreases, which can affect the direction and rate of a reaction and thus the Pt potential.

5. What factors can cause fluctuations in Pt potential?

Factors such as temperature, concentration of reactants and products, pH, and the presence of catalysts or inhibitors can all affect Pt potential. Changes in these factors can alter the reaction quotient and thus the measured potential.

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