X-ray question about form factors

In summary, to calculate the form factor, we used the equation f(x) = ∫ρ(r)exp(-2πix·r) dV and assumed that He has a hydrogenic ground state with electron density ρ(r) = (1/πa0^3)exp(-r/a0). After substituting this into the equation, we performed the integration to arrive at the final expression for the form factor.
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Homework Statement



Make an approximate calculation of the x-ray atomic form factor for He by assuming that its electron density is given by a hydrogenic ground state.

Homework Equations



Need help with this.

The Attempt at a Solution



I attempted to use the hydrogenic model, but could not figure out how to do this. There are additional parts to this question, but I just need a little help on getting started so that I can get this part, and then I can do the parts that follow. Thank you.
 
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To calculate the x-ray atomic form factor for He, we can use the following equation:

f(x) = ∫ρ(r)exp(-2πix·r) dV

where f(x) is the form factor, ρ(r) is the electron density, and x is the scattering vector.

Since we are assuming that He has a hydrogenic ground state, we can use the following expression for the electron density:

ρ(r) = (1/πa0^3)exp(-r/a0)

where a0 is the Bohr radius.

Substituting this into the equation for the form factor, we get:

f(x) = (1/πa0^3)∫exp(-r/a0)exp(-2πix·r) dV

We can rewrite this as:

f(x) = (1/πa0^3)∫exp[-(r/a0 + 2πix·r)] dV

Using the spherical coordinates, we can write dV as r^2sinθdrdθdφ.

Substituting this into the equation, we get:

f(x) = (1/πa0^3)∫r^2sinθexp[-(r/a0 + 2πix·r)] drdθdφ

The integration over φ and θ will give us constants, so we can write:

f(x) = (1/πa0^3)∫r^2exp[-(r/a0 + 2πix·r)] dr

We can now substitute r = u/a0, and the integral becomes:

f(x) = (1/πa0^3)∫u^2exp(-u - 2πix·a0u) du

This integral can be evaluated using integration by parts, and the final expression for the form factor is:

f(x) = (1/πa0^3)[(1 + 2πix·a0)^-3]

This is the approximate calculation of the x-ray atomic form factor for He.
 

1. What are form factors in X-ray analysis?

Form factors in X-ray analysis refer to the mathematical expressions that describe the scattering of X-rays by the electrons within an atom. These form factors are used to calculate the intensity of the scattered X-rays and provide information about the structure and composition of materials.

2. How are form factors calculated?

Form factors are calculated using the atomic scattering factors, which are determined by the electron density distribution of the atoms in a material. These factors are then combined with the scattering angle and the wavelength of the X-rays to calculate the form factor.

3. What is the significance of form factors in X-ray crystallography?

In X-ray crystallography, form factors are essential for determining the positions of atoms within a crystal lattice. By analyzing the diffraction pattern produced by the scattered X-rays, the form factors can be used to determine the electron density and therefore the positions of the atoms in the crystal.

4. Can form factors be used to identify different elements in a material?

Yes, form factors can be used to identify different elements in a material. Each element has a unique form factor, and by comparing the measured form factors with a database of known elements, the composition of a material can be determined.

5. How are form factors affected by temperature and pressure?

Temperature and pressure can affect the form factors of materials in different ways. In general, as temperature increases, the form factors decrease due to the increased thermal motion of the atoms. Pressure can also affect the form factors, as the compression of a material can change the electron density distribution and therefore the scattering behavior of X-rays.

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