Why is Fermi Level constant across pn junction?

In summary, the Fermi Level is a constant energy level in a pn junction that is maintained by the diffusion of electrons between the n-type and p-type regions. This creates a built-in potential barrier, allowing the pn junction to act as a diode. However, the Fermi Level can change when an external voltage is applied. It is only constant in equilibrium conditions and has significant implications in determining the behavior and properties of semiconductor devices.
  • #1
chingkui
181
2
I know this is true under thermal equilibrium, but I am not sure why. Why can't the Fermi level be a function of position relative to the pn-junction? How does that follow from thermodynamics/statistical mechanics?
 
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  • #2
If you have (more than 50% occupancy at energy E) on one side and (less than 50% occupancy at energy E) at the other side, the system is not in equilibrium, and electrons can move from one side to another, increasing entropy and reducing the energy of the system.
 

1. Why is the Fermi Level constant across a pn junction?

The Fermi Level is the energy level at which there is a 50% probability of finding an electron in a material. In a pn junction, there is a diffusion of electrons from the n-type region to the p-type region and vice versa. This diffusion creates an electric field which balances the potential difference between the two regions, resulting in a constant Fermi Level.

2. How does the constant Fermi Level affect the behavior of a pn junction?

The constant Fermi Level creates a built-in potential barrier at the junction, preventing further diffusion of electrons. This is what allows a pn junction to act as a diode, allowing current to flow in only one direction.

3. Can the Fermi Level change in a pn junction?

The Fermi Level can change if an external voltage is applied to the pn junction. This changes the potential difference between the two regions and can result in the Fermi Level shifting towards one side or the other.

4. Is the Fermi Level constant in all types of junctions?

No, the Fermi Level is not constant in all types of junctions. It is only constant in equilibrium conditions, where there is no external voltage applied. In non-equilibrium conditions, such as when a voltage is applied, the Fermi Level can change.

5. What is the significance of the constant Fermi Level in semiconductor devices?

The constant Fermi Level allows for precise control of the behavior of a pn junction, making it a crucial component in many semiconductor devices. It also plays a role in determining the energy levels of electrons in different materials, which affects their conductivity and other properties.

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