Soluble metal ion to make heavy water?

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Discussion Overview

The discussion centers around the search for a soluble metal ion that could be used to create an alternative to heavy water, with a focus on non-toxic options that could potentially reduce the height necessary for a water experiment requiring significant pressure. The conversation explores various solutes and their properties in relation to the experiment's requirements.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant inquires about a soluble metal ion additive for creating an alternative heavy water, noting that heavy water uses deuterium.
  • Another participant suggests common salt as a soluble option, highlighting its availability and solubility, while also mentioning Epsom salts.
  • A different participant challenges the initial premise, stating that heavy water is not similar to the proposed additive solute and questions the purpose of the inquiry.
  • One participant clarifies that the goal is to reduce the height necessary for a water experiment, which would allow for a smaller apparatus, and expresses a preference for a more inert substance than chlorine.
  • Another participant proposes lithium heteropolytungstate solutions as a potential option, noting concerns about cost and toxicity.
  • Mercury is mentioned as a heavy option, but its use is cautioned against due to toxicity.
  • Participants discuss the nature of the experiment, clarifying that it is flow-based and expressing concerns about the challenges of maintaining constant pressure and flow without toxic additives.

Areas of Agreement / Disagreement

Participants express differing views on the suitability of various solutes, with no consensus on a specific solution. The discussion remains unresolved regarding the best approach to achieve the desired experimental conditions.

Contextual Notes

Participants note limitations regarding the toxicity of certain additives and the specific requirements of the experiment, including flow rates and pressure ranges, which remain unclear.

Another God
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Hi people. I am asking this for a friend, and he's not here right now, so I'm doing my best to remember exactly what it was that he was looking for, but I know that he is looking for something which is soluble, and I think he said Metal Ion, which is non-toxic etc, that can be used to make heavier water...

I know 'Heavy Water' uses Deuterium (Or whichever Isotope of Hydrogen it is), but I think he is looking for some additive solute to achieve a similar ends...

Anyone have any ideas? How do u make an alternative heavy water?
 
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Common salt. Very soluble, actually shrinks the volume of water, adds sodium and chlorine ions to the water. Other salts might be more soluble and more massive, but table salt is very easy to obtain. Also epsom salts would do. You can get them at the drug store.

Njorl
 
Originally posted by Another God
I know 'Heavy Water' uses Deuterium (Or whichever Isotope of Hydrogen it is), but I think he is looking for some additive solute to achieve a similar ends...
"Heavy water" isn't at all similar to what you described in your first paragraph. It isn't noticeably different from regular water unless you have a pretty accurate scale.

Salt is highly soluble in water and you could probably double the weight density by dissolving enough salt in it.

What exactly is the point of this? It may help us help you.
 
He is looking to reduce the height necessary for a water experiment which requires significant pressure head height to behave properly. If he can reduce the head height/pressure then the apparatus can be made smaller. Also Chlorine is very corrosive so something more inert would be nice. Something heavier than sodium would also be an advantage.

Thanx
 
Static pressure, or is this a flow type experiment?
 
Does it have to be a liquid manometer? How about an electronic one?
 
Originally posted by Another God
He is looking to reduce the height necessary for a water experiment which requires significant pressure head height to behave properly. If he can reduce the head height/pressure then the apparatus can be made smaller. Also Chlorine is very corrosive so something more inert would be nice. Something heavier than sodium would also be an advantage.

Thanx

Lithium heteropolytungstate solutions would do. They might be expensive to obtain, and have some toxicity issues though.

Of course, there's always mercury, but it would probably be better not to mess with it.

Njorl
 
Originally posted by Bystander
Static pressure, or is this a flow type experiment?
It's flow based.

And the toxic additives aren't really options, but thanks for trying Njorl
 
This is starting to sound ugly --- flow, constant(?) head, and no additives --- can he (she? it?) stand the chatter from a regulator? or, is part of the experiment the milimetric uncertainty of a constant head device? Flow AND constant pressure are a tough order at the lab scale --- slip us a little more in the way of specs --- flow rate ranges, pressure ranges, acceptable uncertainties at the range extremes.
 

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