Register to reply

Thickness of oxidation layer on fuel elements.

by vanesch
Tags: elements, fuel, layer, oxidation, thickness
Share this thread:
vanesch
#1
Mar14-08, 05:15 AM
Emeritus
Sci Advisor
PF Gold
P: 6,236
I have a question: it is generally stated that 100 micrometers is the acceptable limit on the thickness of the oxidation layer on Zircaloy4 fuel rods. But I'm at loss as what is the reason for this limit ? Is it structural integrity ? Thermal resistance ? Mechanical tolerance ?
Phys.Org News Partner Science news on Phys.org
NASA team lays plans to observe new worlds
IHEP in China has ambitions for Higgs factory
Spinach could lead to alternative energy more powerful than Popeye
Homer Simpson
#2
Mar17-08, 11:00 AM
P: 191
I've never really heard of a limit on ZrO2 layer, so my input is just for conversation.

A little oxide layer is a good thing: prevents the zirconium steam reaction at elevated sheath temps.

but like you say, if too much Zr is oxididized, it would be brittle with poor heat transfer.
Astronuc
#3
Mar17-08, 11:22 AM
Admin
Astronuc's Avatar
P: 21,808
Quote Quote by vanesch View Post
I have a question: it is generally stated that 100 micrometers is the acceptable limit on the thickness of the oxidation layer on Zircaloy4 fuel rods. But I'm at loss as what is the reason for this limit ? Is it structural integrity ? Thermal resistance ? Mechanical tolerance ?
It's mainly about structural integrity, but it's also about thermal resistance as it effects the cladding temperature, which affects structural integrity if rod internal pressure exceeds critical limit (lift-off).

That limit is somewhat arbitrary, and has received a lot of study in the last decade as a result of two concerns - 1) the response of the cladding to RIA transients and 2) response of cladding to LOCA and subsequent quenching when cooler water is introduced to the core.

Way back in the good old days, Westinghouse set limit of 100 microns which was calculated to yield an average value of 600 ppm H in the cladding wall. That value is based upon a hydrogen pickup rate (~0.15 - 0.17) during the course of operation. The actual H-pickup ratio is highly variable and has dependence on water/oxide chemistry. Hydrogen embrittlement is an issue at low temperatures.

In the past 15 years, there has also been increased attention to the spallation of cladding oxide, which can result in local cool areas on the cladding with the result the hydrogen migrates from the surronding area to the cooler area. Significant hydrogen (1000-3000 ppm), and this could present a problem for structural integrity under certain off-normal conditions (e.g. RIA) and potentially at high burnup during a power increase (e.g. so-called 'out-to-in' failures).

Westinghouse has developed ZIRLO (Zr-Nb-Sn-Fe) alloy and AREVA has developed M5 (Zr-Nb-O) alloy in order to reduce both the oxide thickness and hydrogen pickup as a function of burnup (exposure).

vanesch
#4
Mar18-08, 12:14 AM
Emeritus
Sci Advisor
PF Gold
P: 6,236
Thickness of oxidation layer on fuel elements.

Ah, so the oxide thickness is taken as a kind of rough measure of hydrogen absorption (which embrittles zirconium, I know). It is not the oxide layer itself which is the main difficulty, but rather the (more difficult to measure) hydrogen intake, but as both are correlated, we put a limit on the easiest observable one, is that it ?
Astronuc
#5
Mar18-08, 09:55 AM
Admin
Astronuc's Avatar
P: 21,808
Quote Quote by vanesch View Post
Ah, so the oxide thickness is taken as a kind of rough measure of hydrogen absorption (which embrittles zirconium, I know). It is not the oxide layer itself which is the main difficulty, but rather the (more difficult to measure) hydrogen intake, but as both are correlated, we put a limit on the easiest observable one, is that it ?
Correct. One can measure the oxide thickness non-destructively, usually with an eddy-current liftoff probe, which is correlated to oxide thickness, as opposed to destructive testing where hydrogen is measured by metallography or hot-extraction (e.g. LECO test).

Eddy-current liftoff measurements must be corrected for the magnetic susceptibility Ipermeability) of the crud on the oxide layer. This has been an issue in plants which use Zn-injection in the primary cooling system. It was first noticed in BWRs, but now that PWRs are using Zn-injection, it is also an issue there.

Helmut Fischer GmbH makes thickness probes -
http://www.helmut-fischer.com/indexC...9&LanguageID=6

There is also the loss of the metal (structure). ZrO2/Zr has a Pilling-Bedworth ratio of about 1.56, so there is that issue to consider in conjunction with the hydrogen.

In high burnup fuel, one may find hydrogen accumulation in the outer surface of the cladding wall, particularly in the region of the cladding adjacent to the pellet-pellet interfaces. It is the localization of hydrogen that is of concern, since that potentially may be the weakest point.

This might be of use (it's dated but informative) -

Waterside Corrosion of Zirconium Alloys in Nuclear Power Plants
IAEA TECDOC Series No. 996
http://www-pub.iaea.org/MTCD/publica...te_996_web.pdf (22.3 MB - use 'save target as')
1998.
vanesch
#6
Mar18-08, 02:00 PM
Emeritus
Sci Advisor
PF Gold
P: 6,236
Quote Quote by Astronuc View Post
I high burnup fuel, one may find hydrogen accumulation in the outer surface of the cladding wall, particularly in the region of the cladding adjacent to the pellet-pellet interfaces. It is the localization of hydrogen that is of concern, since that potentially may be the weakest point.
Yes, I remember that somewhere: it is due to the slightly lower temperature and a preferred migration of the hydrogen towards the cooler regions, no ?

This might be of use (it's dated but informative) -

Waterside Corrosion of Zirconium Alloys in Nuclear Power Plants
IAEA TECDOC Series No. 996
http://www-pub.iaea.org/MTCD/publica...te_996_web.pdf (22.3 MB - use 'save target as')
1998.
Wow! The "everything you wanted to know about zirconium but didn't dare to ask" volume

Thanks a lot!
Astronuc
#7
Mar18-08, 02:57 PM
Admin
Astronuc's Avatar
P: 21,808
Yes, hydrogen migrates from the hotter regions to the cooler regions where it precipitates as ZrH2, Zr hydride, which while it acts like a matrix stiffener (like a whisker with a high modulus), it also gives rise to local stresses. Furthermore, the migration of H through the metal leaves a high concentration of dislocations, which IMO can promote crack nucleation under the right conditions.

TECDOC 996 is a great overview of the state of the art in 1998. I know most of the people who co-authored that document and who are cited within.

We actually need an update since there has been a lot of work in the last decade on the subject.
Homer Simpson
#8
Mar18-08, 05:47 PM
P: 191
Quote Quote by Astronuc View Post
Furthermore, the migration of H through the metal leaves a high concentration of dislocations, which IMO can promote crack nucleation under the right conditions.
as an aside, that sounds a bit like the method thru which 'delayed hydride cracking' can occur in Zr pressure tubes. As the unit comes down below 200 degrees C or so, the hydrogen which has migrated to cool/high stress areas comes out of solution leaving Zr hydride platelets, which are brittle, and will crack from the process pressure in the tube. This crack acts as a stress riser, attracting more hydride on the next cool down cycle.
Astronuc
#9
Mar18-08, 05:56 PM
Admin
Astronuc's Avatar
P: 21,808
Quote Quote by Homer Simpson View Post
as an aside, that sounds a bit like the method thru which 'delayed hydride cracking' can occur in Zr pressure tubes. As the unit comes down below 200 degrees C or so, the hydrogen which has migrated to cool/high stress areas comes out of solution leaving Zr hydride platelets, which are brittle, and will crack from the process pressure in the tube. This crack acts as a stress riser, attracting more hydride on the next cool down cycle.
It's the cycling of temperature, which drives the cycle of solution and precipitation (or resolution/re-precipitation) of the hydrides that drives DHC (delayed hydride cracking). Even though the Zr-Nb (or Zr-2) pressure tubes have low oxide thickness, they have a relatively large surface area, and IIRC it was the cold (inlet) end that had the DHC.

There is a similar mechanism in failed fuel, which is more of a HACP (hydrogen-assisted crack propagation).


Register to reply

Related Discussions
Boundary Layer displacement thickness Mechanical Engineering 1
Smallest Possible N-Fuel Elements? Nuclear Engineering 9
Stiochiometric air-to-fuel ratio for heavy fuel oil Engineering Systems & Design 2
Turbulent Boundary layer thickness on a flat plate Mechanical Engineering 1
Final storage containing spent HTR fuel elements Nuclear Engineering 3