What Happens When I Light a Match in Hydrogen-Filled Room?

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Discussion Overview

The discussion explores the hypothetical scenario of lighting a match in a room filled entirely with hydrogen, focusing on the chemical reactions involved and the conditions necessary for ignition and combustion.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation

Main Points Raised

  • Some participants suggest that without an oxidizer, very little would happen when lighting a match in a hydrogen-filled room.
  • One participant questions whether a match would even ignite in the absence of oxygen, while another asserts that matches can strike in a vacuum but will extinguish quickly.
  • There is a discussion about the oxidizers present in matches, with a participant explaining that matches contain oxidizers that allow them to burn without atmospheric oxygen.
  • A participant references the explosive limits of hydrogen-oxygen mixtures, noting that ignition requires a specific range of oxygen concentration, and speculates on the potential for other chemical reactions involving hydrogen.

Areas of Agreement / Disagreement

Participants express differing views on the ignition of matches in a hydrogen environment, with no consensus on whether any significant reaction would occur without sufficient oxidizer present.

Contextual Notes

Some assumptions about the nature of matches and the conditions required for combustion remain unresolved, particularly regarding the role of oxidizers and the specific reactions that may occur in a hydrogen atmosphere.

datatec
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What would happen if I lit a match in an air-tight room completely filled with hydrogen?
 
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With no oxidizer present, very little would happen.

- Warren
 
would the match even light if there was no oxygen in the room?
 
ExtravagantDreams said:
would the match even light if there was no oxygen in the room?

yes
when I was 8 years old the 7 year old next door to us down the street
performed an experiment with wooden strike-anywhere "kitchen matches"
that demonstrated this, which was not a good thing

all the matches I know of have the oxidizer mixed in
like in gunpowder there is KNO3 which will not burn but
which will supply oxygen to charcoal powder so that the charcoal will burn
that is roughlyspeaking why you mix KNO3 with charcoal (and sulphur)
to make black gunpowder

you don't have to have air in order to have an oxidation reaction
matches would strike in a vacuum, and flare briefly but quickly go out
 
Last edited:
The explosive region of the hydrogen-oxygen mixture diagram is between about 10% and 90% oxygen - if I recall correctly. With less or more oxygen than that you don't get an explosion.

You could get some oxygen from outgassing from the match (matchbook) or your breathing apparatus, but it probably won't be enough to ignite the hydrogen.

I'm not sure if other reactions are possible, though. For instance, under the right conditions, hydrogen will reduce carbon dioxide to carbon monoxide (or even plain carbon ?) and water vapor. I'm not sure of the energetics for that reaction.
 

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