Writing balanced net ionic equations

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Discussion Overview

The discussion revolves around writing balanced net ionic equations for specific redox reactions in acidic solution. Participants seek assistance in identifying the correct equations for three distinct chemical reactions involving phosphorus, tellurium, and bromine.

Discussion Character

  • Homework-related
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant requests help with balancing net ionic equations for three reactions, specifically in acidic conditions.
  • Another participant emphasizes the importance of understanding the redox states of the reactants and products to determine electron transfer in the reactions.
  • A participant expresses confusion about the appearance of electrons in the first reaction, questioning the balancing process.
  • One participant notes that the reaction medium (acidic or basic) must be considered when writing ionic equations, suggesting the addition of water and H+ or OH- ions for proper balancing.

Areas of Agreement / Disagreement

Participants generally agree that the reactions are redox in nature and that the reaction medium is significant for balancing. However, there is uncertainty regarding the specifics of electron transfer and the balancing of the first reaction.

Contextual Notes

Participants have not reached a consensus on the balanced equations, and there are unresolved questions regarding the electron transfer in the reactions.

starsun
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can anyone write the balanced net ionic equations for the following reactions in acid solution?? thanks.. i can't figure it out

1. solid phosphorus (P4) reacts with hypochlorous acid (HClO) to form phosphoric acid H3PO4, and chloride ion

2. Tellurium, Te, is oxidized by nitrate ion to form solid tellurium dioxide and NO

3. An acqueous solution of bromine is reduced to Br-, at the same time iodide ions are oxidized to iodate ions, IO3-
 
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what can't you figure out?
 
They are redox reactions, so be sure to know the starting and end products' redox states, this is a must if you want to know where electrons go.
 
starsun said:
can anyone write the balanced net ionic equations for the following reactions in acid solution?? thanks.. i can't figure it out

1. solid phosphorus (P4) reacts with hypochlorous acid (HClO) to form phosphoric acid H3PO4, and chloride ion

2. Tellurium, Te, is oxidized by nitrate ion to form solid tellurium dioxide and NO

3. An acqueous solution of bromine is reduced to Br-, at the same time iodide ions are oxidized to iodate ions, IO3-

I agree that they are redox and that the hypochlorous acid (HClO) is in AQUEOUS solution,but still that doesn't accoun for the electron which pops outta no where at #1.

Daniel.
 
The unstated part of an ionic reaction is the reaction medium, which may be acidic or basic (in the absence of specification, you may use either notation).

So, in addition to the given reactants and products, you must add water and H+ (or OH-) ions to the reaction to balance it.

So, for example in #1, above, you will find that you must use (per mole of P4) 6 moles of water, resulting in 10 moles of H+ (and Cl-, of course). Alternatively, you may add 4 moles of OH- and get 10 moles of water.
 

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