Register to reply 
Question about Bragg diffraction 
Share this thread: 
#1
Apr2914, 08:15 AM

PF Gold
P: 101

For diffraction to occur in crystal, Bragg equation must be satisfied and h,k,l must be of certain combination. I would like to ask
1. How to distinguish a second order diffraction of (100) and first order diffraction of (200)? (they occurs at the same angle.) 2. How can a (200) plane diffraction of simple cubic possible? It seems that there is no atom from this plane because atom only at the four corners of a unit cell. 


#2
Apr3014, 10:10 AM

PF Gold
P: 101

Some may say that the (200) diffraction is actually the second order (100), but it seems that the (200) plane simply doesn't exist. FCC and BCC also have this problem.



#3
May114, 02:53 AM

Sci Advisor
Thanks
PF Gold
P: 1,908

The Bragg reflections for first order: λ=2 d sin(Θ);
for higher orders (=n) we have: nλ=2 d sin(Θ). The diffraction angle increases with the increase in n; thus the (222) reflection appears further out than the (111) reflection  however, in general it will be much weaker. When you look at the families of possible crystal planes the simple cubic (100) includes every plane parallel to this surface; the (200) includes every other such plane; the (600) includes every 6th plane  these higher orders cover the cases where the intervening planes are "missed" by the incoming radiation; this must be possible for the Bragg equation to work: the model is based on "partially reflecting" surfaces, which are the planes. In reciprocal space these planes are closer and closer together by the reciprocal ratio: the (200) family is twice as close together as the (100) family. Kittel's "Introduction to Solid State Physics" goes over most everything you would need to know in an easy to understand fashion. 


#4
May114, 03:16 AM

PF Gold
P: 101

Question about Bragg diffraction
Thanks. I understand that every higher order (n) diffraction of (hkl) can be represented by (nh nk nl) diffraction. The existence of (nh nk nl) diffraction can also be proved even the limitation of h,k,l combination are considered (e.g. h+k+l must be even for BCC).
What I still wondering is that how can we tell whether a plane exist? Does it necessarily have a set of atoms whose centers lying on that plane (like (100) in simple cubic) or if diffraction can occur then the plane exist even there is no atoms lying on that plane (like (200) in simple cubic)? 


#5
May114, 03:36 AM

Sci Advisor
Thanks
PF Gold
P: 1,908

Do you mean the selection rules, or the physical presence of the plane?
For the (100) plane you can consider just the unit cell; for the (200) plane you simply stack two unit cells, etc. You won't run out of planes until you run out of atoms in the crystal ... there are usually more than enough, even in tiny crystallites. However, most of the beam energy is diffracted away by the lower order planes, so the higher orders become fainter and fainter  it often requires a time exposure to make them visible. 


#6
May114, 03:57 AM

PF Gold
P: 101




#7
May114, 01:15 PM

Sci Advisor
Thanks
PF Gold
P: 1,908

And they are easy to find because they only require two layers of the crystal. You would do well to read a text book like Kittel in order to improve your visualization; it does take a while to get used to crystallography and Miller indices and Bragg diffraction. Perhaps this: http://www.slideshare.net/joserabelo...ractionbasics 


Register to reply 
Related Discussions  
Xray Diffraction and Bragg's Law  Advanced Physics Homework  0  
A Question about microwave diffraction (Bragg scattering)  Advanced Physics Homework  0  
Bragg Diffraction Help  Introductory Physics Homework  1  
Bragg Diffraction  Physics Learning Materials  0  
Bragg's Diffraction  Introductory Physics Homework  0 