Volume of Brillouin zone is the same as Fourier primitive parallelepip

In summary, in Kittel's solid state text, problem 2.3, it is stated that the volume of the Brillouin zone is equivalent to a primitive parallelepiped in Fourier space. However, the reason for this is not immediately apparent. The same relationship holds true between Wigner-Seitz cells and primitive parallelepiped in real space, and this is easier to visualize. Both the WS-cell and primitive unit cell contain the basis of the crystal structure once, allowing for conversion between the two by cutting, translating, and pasting.
  • #1
ZetaOfThree
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In Kittel's solid state text, problem 2.3, he says that the volume of the Brillouin zone is the same as a primitive parallelepiped in Fourier space. Somehow I can't see why this is true. Can someone help me see why this is true? Also, is the same relationship true between Wigner-Seitz cells and primitive parallelepiped in real space?

Thanks
 
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  • #2
The same is true for the cells in real space, and it is perhaps easier to see in real space.

By construction, the Wigner-Seitz cell contains the basis of the crystal structure exactly once. This is also true for any primitive unit cell. It follows that it must be possible to convert the WS-cell into any primitive cell by cutting, translating by a lattice vector, and pasting parts.

Hope this helps.
 

1. What is the definition of a Brillouin zone?

A Brillouin zone is a region in reciprocal space that represents all the possible wave vectors of electrons in a crystal lattice. It is used to understand the electronic properties of materials.

2. What is the relationship between the volume of a Brillouin zone and the primitive parallelepiped in Fourier space?

The volume of a Brillouin zone is equal to the volume of the primitive parallelepiped in Fourier space. This means that the size and shape of the Brillouin zone can be determined by the dimensions of the primitive parallelepiped.

3. How does the volume of a Brillouin zone affect the electronic properties of a material?

The volume of a Brillouin zone is directly related to the density of states and the band structure of a material. A larger Brillouin zone can accommodate more energy levels, leading to a higher density of states and potentially more complex band structures.

4. What is the significance of the volume of a Brillouin zone being the same as the primitive parallelepiped in Fourier space?

This relationship is important because it allows for a direct translation between real and reciprocal space. It also provides a convenient way to visualize and understand the electronic properties of materials in terms of their Fourier components.

5. Can the volume of a Brillouin zone be changed?

Yes, the volume of a Brillouin zone can be altered by changing the dimensions of the primitive parallelepiped in Fourier space. This can be achieved by applying external forces or by modifying the crystal structure of the material.

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