Calculating Density of Oxygen at STP

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Homework Help Overview

The discussion revolves around calculating the density of oxygen gas at standard temperature and pressure (STP) using the ideal gas law. Participants are exploring how to apply the formula and what values are necessary for the calculation.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the application of the ideal gas law (PV=nRT) and question how to determine the number of moles (n) and the appropriate molecular mass for oxygen. There is uncertainty about whether to use 1 mole or another value for n, and whether additional information is needed for the calculation.

Discussion Status

Some participants have provided guidance on using the molar volume at STP and the correct molecular mass of oxygen. There are multiple interpretations regarding the calculation of moles and density, and the discussion is ongoing without a clear consensus.

Contextual Notes

Participants are addressing potential confusion regarding the molecular mass of oxygen and the need for accurate values in the ideal gas law. There is mention of a periodic chart and the importance of using correct units for calculations.

tomrh3
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Ok, I know I have to use the ideal gas law, but am not exactly sure how to apply that to finding the density.

PV=nRT (ideal gas law)

1atm (volume) = n(number of moles - can I just use 1 for ease?)(8.315 J(mol•K) (temperature)

Not quite sure where to go from here, any help would be appreciated just to get me in the right direction. Do I need the density of Oxygen at another temperature in order to do this?
 
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Tom,
density of an element at stp is its mass/volume.
Since-breathable- oxygen is 2 atoms at standard temp(293-298K) and pressure(1atm), you need to account for O2-- 16 grams per mole, i.e., n=2.
Do you have the "unit" volume?
nrt/p = V.
you can get its atomic mass from the periodic chart.
A decent (one bought from the college bookstore for $5.00) chart would also have the unit density on it as well.
Hope this is helpful.
 
SteveDB said:
Tom,
Since-breathable- oxygen is 2 atoms at standard temp(293-298K) and pressure(1atm), you need to account for O2-- 16 grams per mole, i.e., n=2.
Do you have the "unit" volume?
nrt/p = V.

Shortly after my post I realized that the atomic mass was the piece that I was missing, so to find n I did n=(mass)/(molecular mass), n=1gram/16, and after plugging that all in, I got a final density of 1.40 (which is basically much that of oxygen). Was I right to use n=1/16 or was it n=2? Thanks for the help.
 
The molar volume at stp is 22.4141L as I recall. This is easily calculated with the ideal gas law using 1 mole and stp, be sure to use correct units for your R. From there the density will be molar mass/molar volume.
 
I found this claculation by chance and I noticed a mistake. Molecular mass for O2 is 32, not 16 because the O2 molecule is formed by two O atoms which mass is 16 each.
 

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