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    Valency and oxidation state in PbTiO3

    I have two related questions on PbTiO3 perovskite structure and chemical environment. The Pb K-egde Xanes data reveals that Pb is in a mixed valence state of Pb4+ and Pb2+. However in literature Pb is claimed to be in Pb2+ state. The Pb 6s2 electrons hybridize with the O 2p electrons to form...
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