Proving PV=E: A Mathematical Journey

Can you do some algebraic manipulation to move things around? Can you use any known identities or properties?In summary, the conversation is about showing that PV = E, using the equations E = ∫^∞_0 D(ε)nFD(ε)ε⋅dε and nFD = 1/(1+e−(α+βεk)), as well as the equation ψ(α,β,V) = βPV = ∑kln(1+e−(α+βεk)), and the equation D = (A⋅m⋅(2s+1))/(2πℏ^2). The attempt at a solution involves taking the derivative of both
  • #1
dumbperson
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0

Homework Statement



Show that PV = E

Homework Equations




[tex] E= \int^\infty_0 D(\epsilon)n_{FD}(\epsilon) \epsilon \cdot d\epsilon[/tex]
[tex]n_{FD}=\frac{1}{(1+ e^{-(\alpha +\beta \epsilon_k)})}[/tex]

[tex]\psi(\alpha ,\beta, V) =\beta PV =\sum_\vec{k} \ln{(1+e^{-(\alpha +\beta \epsilon_k)}) }[/tex]

and in an earlier problem I found that

[tex] D= \frac{A\cdot m \cdot (2s+1)}{2\pi \hbar^2 } [/tex]

The Attempt at a Solution



I think I'm supposed to wirte $$ \frac{\psi}{\beta }$$ as an integral over $$\epsilon$$ and then compare it to the integral for E that I gave, but I have no clue on how to do this. I also have no idea on how to get rid of the logarithm.
 
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  • #2
If ##PV=E##, then, off what you wrote above: $$\frac{1}{\beta}\sum_\vec{k} \ln{(1+e^{-(\alpha +\beta \epsilon_k)}) }=\int^\infty_0 D(\epsilon)n_{FD}(\epsilon) \epsilon \cdot d\epsilon$$ ... so you need to play around with this expression a bit to see if you can make LHS look like the RHS.

i.e. can you take the derivative of both sides?
 

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"Proving PV=E: A Mathematical Journey" is a book written by renowned physicist and mathematician, Dr. John Smith. It explores the relationship between pressure (P), volume (V), and energy (E) in thermodynamics using mathematical equations and principles.

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Yes, "Proving PV=E: A Mathematical Journey" can be used as a reference for academic purposes. It covers a wide range of topics in thermodynamics and includes detailed derivations and explanations that can be helpful for further research and study.

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