What is the Correct Hamiltonian for an Isolated Gas and Piston System?

In summary, the task is to use the microcanonical ensemble to deduce the equation of state for pressure in an isolated system consisting of a box, movable piston, and an object with weight W placed on the piston. The equations used in this problem are the Hamiltonian, partition function, entropy, and the derivative of entropy with respect to volume. The main challenge is solving the integral for the number of microstates.
  • #1
luisgml_2000
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Homework Statement



A system is contained within the walls of a box and a movable piston. An object weighing W is placed on the piston. If you regard the gas and the piston as an isolated system, use the microcanonical ensemble to deduce the equation of state for p (pressure). Take a look at the picture.


Homework Equations



[tex]\mathcal{H}=\frac{1}{2m}\sum p_i^2 + Wx[/tex]

[tex]\Omega=V^{n}\int_{\mathcal{H} <E}dx d^{3N}p[/tex]

[tex]S=klog\Omega[/tex]

[tex]p/V=\frac{\partial S}{\partial V}[/tex]

The Attempt at a Solution



The only thing I need to solve this problem is to write down the hamiltonian of this system. I'd like to know if the expression that I have written is correct; in that case, I don't know how to evaluate the integral for the number of microstates.

thanks!
 

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  • #2
I'm sure that the hamiltonian of this system is as written above. Do you have any ideas for solving the integral for [tex] \Omega[\tex]?
 

What is a slightly modified ideal gas?

A slightly modified ideal gas is a theoretical model used to describe the behavior of gases under certain conditions. It is an extension of the ideal gas law, which assumes that gas particles have no volume and do not interact with each other.

How is a slightly modified ideal gas different from an ideal gas?

The main difference is that a slightly modified ideal gas takes into account the size of gas particles and their interactions with each other. This makes it a more accurate model for gases at high pressures or low temperatures, where the ideal gas law fails.

What are the assumptions of a slightly modified ideal gas?

The assumptions include that the gas particles have a finite size, that there are intermolecular forces between particles, and that the gas is in thermal equilibrium. It also assumes that the particles are constantly moving and colliding with each other and the walls of the container.

What are the applications of a slightly modified ideal gas?

A slightly modified ideal gas is used in various fields such as thermodynamics, chemical engineering, and atmospheric science. It is also used in the design of gas storage tanks and pipelines, and in the study of planetary atmospheres.

What are the limitations of a slightly modified ideal gas?

While it is more accurate than the ideal gas law, a slightly modified ideal gas still has limitations. It does not take into account quantum effects or non-ideal behaviors such as phase transitions. It also assumes that the gas is in a closed system, and does not account for external factors such as gravity or magnetic fields.

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