Can ABA Arrangements Switch to ABC Arrangements in Crystals?

  • Thread starter MotoPayton
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In summary, ABC closest packing and ABA closest packing are types of arrangements of spheres or atoms that differ in the placement of the third layer. While ABC closest packing places the third layer in the depressions of the second layer, ABA closest packing places it in the depressions of the first layer again. Both have similar properties, including high packing density and a close-packed structure, and are commonly observed in nature. They are also used in materials science to study and develop new materials with specific properties.
  • #1
MotoPayton
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When looking at the ABA and ABC arangments I was wondering if an ABA arrangement can switch to a ABC arrangement in the same crystal.

What would keep the spheres from randomly switching between these two patterns.

From what I understand the 3rd layer always has two options..
 
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  • #2
Whilst the two arrangements probably have similar energy (from what I remember), there is probably an energy barrier between the two, a bit like the inversion of phosphines (or amines, except this is much lower)
 
  • #3
In many substances this swiching happens, e.g. SiC.
 

1. What is ABC closest packing?

ABC closest packing refers to a type of arrangement of spheres or atoms where the first layer is formed by placing spheres in a hexagonal arrangement, the second layer is formed by placing spheres in the depressions of the first layer, and the third layer is formed by placing spheres in the depressions of the second layer. This pattern continues, with each layer being placed in the depressions of the layer below it.

2. What is ABA closest packing?

ABA closest packing is a type of arrangement of spheres or atoms where the first layer is formed by placing spheres in a hexagonal arrangement, the second layer is formed by placing spheres in the depressions of the first layer, and the third layer is formed by placing spheres in the depressions of the first layer again. This pattern then repeats, with each layer being placed in the depressions of the layer below it.

3. How do ABC and ABA closest packing differ?

The main difference between ABC and ABA closest packing is the placement of the third layer. In ABC closest packing, the third layer is placed in the depressions of the second layer, while in ABA closest packing, the third layer is placed in the depressions of the first layer again. This results in a different overall pattern and arrangement of the spheres or atoms.

4. What are the properties of ABC and ABA closest packing?

Both ABC and ABA closest packing have similar properties, including high packing density and efficient use of space. This makes them commonly observed in nature, such as in the arrangement of atoms in crystals. They also have a close-packed structure, with each sphere or atom being in contact with six other spheres or atoms in the same layer and three spheres or atoms in the layer above and below.

5. How are ABC and ABA closest packing used in science?

ABC and ABA closest packing have various applications in science, particularly in the field of materials science. They are used to study the properties of materials, such as their mechanical strength and thermal conductivity. They are also used in the development of new materials with specific properties, such as lightweight and strong materials for aerospace applications.

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