Understanding Bomb Calorimeters: Measuring ΔE and ΔH for Calorimetry Homework

In summary, a bomb calorimeter is a device used in chemical experiments to measure the amount of heat released or absorbed during a reaction. It works by isolating the reaction inside the bomb from the surroundings, and uses the change in temperature of the surrounding water to calculate the heat energy involved. The terms ΔE and ΔH are used in calorimetry to measure changes in internal energy and enthalpy, respectively. Using a bomb calorimeter is important in experiments for precise and accurate measurement of heat energy. Some potential sources of error in bomb calorimetry include incomplete combustion, heat loss, and measurement errors. Proper insulation and careful measurement are important to minimize these errors.
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henry3369
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Homework Statement


My book says that bomb calorimeters are used to measure ΔE while coffee cup calorimeters are used to measure ΔH. Isn't ΔE for bomb calirometers the same as ΔH?

Homework Equations

The Attempt at a Solution


Bomb Calorimeter:
ΔH = ΔE + PΔV = ΔE (since, constant volume).
So ΔH = ΔE.
So does that mean no work is done in bomb calorimeters and the change in energy is entirely due to the transfer of thermal energy?
 
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  • #2
You have written wrong equation.
It is actually ΔH= ΔE + ΔPV
 
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1. What is a bomb calorimeter?

A bomb calorimeter is a device used in chemical experiments to measure the amount of heat released or absorbed during a reaction. It consists of a strong steel container, known as a bomb, that is filled with the reactants and placed in a surrounding water bath. The change in temperature of the water is then used to calculate the heat released or absorbed by the reaction.

2. How does a bomb calorimeter work?

A bomb calorimeter works by isolating the reaction taking place inside the bomb from the surrounding environment. The bomb is placed in a water bath, which acts as an insulator, preventing any heat from escaping. As the reaction takes place, the heat released or absorbed causes a change in temperature of the water, which can then be measured and used to calculate the amount of energy involved in the reaction.

3. What is the difference between ΔE and ΔH in calorimetry?

ΔE (Delta E) refers to the change in internal energy of a system, while ΔH (Delta H) refers to the change in enthalpy. In calorimetry, these terms are used to measure the change in heat energy during a reaction. ΔE takes into account the heat transferred between the system and its surroundings, while ΔH also considers any changes in pressure or volume of the system.

4. Why is it important to use a bomb calorimeter in experiments?

A bomb calorimeter is important in experiments because it allows for precise and accurate measurement of heat energy in chemical reactions. By using an isolated system, the bomb calorimeter prevents any heat from escaping, providing more reliable results. This is especially important in experiments involving highly exothermic or endothermic reactions.

5. What are some potential sources of error in bomb calorimetry?

Some potential sources of error in bomb calorimetry include incomplete combustion of reactants, heat loss to the surroundings, and measurement errors. It is important to properly insulate the bomb and water bath to minimize heat loss, and to carefully measure the reactants and their quantities to ensure the most accurate results.

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