Calculating Diffusion Coefficient for TiAlN Alloy Coating

In summary, the diffusion coefficient of the TiAlN alloy coating is 21.1 cm²/s, which is significantly lower than that of the steel tank, making it an effective solution for improving hydrogen storage.
  • #1
mmoadi
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Homework Statement



Constant for the diffusion of hydrogen through steel is D(steal) = 4 x 10^5 cm²/s. They try to improve steel tanks for hydrogen storage by applying the coating based on TiAlN alloys. What is the diffusion coefficient Dp of such coating, if the permeability of hydrogen is reduced by 19,000 times? In this attempt the steel had a thickness of
d(steal) = 0.5 mm, and the thickness of the alloys was d(alloy)= 10 nm.

Homework Equations



s²= 2Dt

The Attempt at a Solution



x= 19,000, D(steal) = 4 x 10^5 cm²/s, s(steal)= 0.5 mm, s(alloy)= 10 nm, D(alloy)= ?

s(steal)²= 2D(steal)t
s(steal)² + s(alloy)²= 2D(alloy)xt

s(steal)²/ [s(steal)² + s(alloy)²]= 2D(steal)t/ 2D(alloy)xt
s(steal)²/ [s(steal)² + s(alloy)²]= D(steal)/ D(alloy)x
D(alloy)= D(steal) [s(steal)² + s(alloy)²]/ s(steal)²x
D(alloy)= 21.1 cm²/s

Are my calculations correct?
Thank you for helping!
 
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  • #2


Yes, your calculations are correct. The diffusion coefficient of the TiAlN alloy coating would be 21.1 cm²/s, which is significantly lower than the diffusion coefficient of the steel tank (4 x 10^5 cm²/s). This means that the coating is effective in reducing the permeability of hydrogen through the steel tank, making it a promising solution for improving hydrogen storage.
 
  • #3


Yes, your calculations appear to be correct. However, it would be helpful to provide units for your final answer (in this case, cm²/s). Additionally, it would be beneficial to include a brief explanation of the steps you took to arrive at your solution, as this helps to show your understanding of the concept. Overall, your response is thorough and demonstrates a good understanding of diffusion coefficients and their application in this scenario.
 

What is diffusion coefficient?

Diffusion coefficient is a measure of how quickly a material diffuses (spreads out) through another material. It is a crucial parameter in understanding processes such as diffusion bonding, heat treatment, and corrosion.

Why is calculating diffusion coefficient important for TiAlN alloy coating?

TiAlN alloy coating is widely used in industrial applications due to its high hardness, wear resistance, and thermal stability. The diffusion coefficient is an essential factor in determining the coating's durability and performance, as it affects the coating's microstructure, adhesion, and diffusion-based processes such as wear and corrosion resistance.

How is diffusion coefficient calculated for TiAlN alloy coating?

The diffusion coefficient for TiAlN alloy coating can be calculated using Fick's laws of diffusion. This involves measuring the diffusion depth of a known amount of diffusing species (e.g., nitrogen) into the coating over time and using mathematical equations to determine the diffusion coefficient.

What factors can affect the diffusion coefficient of TiAlN alloy coating?

The diffusion coefficient for TiAlN alloy coating can be affected by several factors such as temperature, composition, microstructure, and coating thickness. These factors can influence the mobility of atoms and the diffusion process, resulting in variations in the diffusion coefficient.

How can knowing the diffusion coefficient of TiAlN alloy coating be beneficial?

Knowing the diffusion coefficient of TiAlN alloy coating can help in optimizing the coating's performance and durability. It can also aid in predicting the coating's behavior under different operating conditions, facilitating material selection and process design, and improving the overall quality and reliability of the coating.

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