Cellulose to Alkane

I'm just curious, what would the process be if someone wanted to change cellulose into an alkane? (I don't plan to try it. If I wanted an alkane then I could just go to the gas station.)
 

alxm

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Can't quite be done really. (in any manner cost efficient enough to be sensible) Cellulose is just a (very branched) sugar chain, so you don't have any individual carbon chains longer than the 6 in glucose, and each of those has a hydroxo group on it, meaning you'd have to reduce that to get an alkane.

For fuel purposes, cellulosic ethanol is where it's at.
 

chemisttree

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I have conducted experiments in which I have successfully converted cellulose into glucose. If you wanted an alkane, in theory, you could oxidize all the -OH of glucose to their respective aldehydes or ketones and treat them with hydrazine/KOH (Wolff-Kishner Reduction) to replace all C=O with H-C-H
 
How did you hydrate the cellulose?
 
Mechanical milling with the aid of a catalyst. I can't really divulge into details because we're submitting the article for publication.
 

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