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Physics
Atomic and Condensed Matter
Confused about population transfer
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[QUOTE="Hyperfine, post: 6861934, member: 731603"] It is question of how the nuclear kinetic energies are treated: how you construct the molecular wave function and how you separate the molecualr geometry variables and the electronic degrees of freedom. The nuclear kinetic energies cannot be neglected in the region of an avoided level crossing. Recasting the Hamiltonian into a diabatic representation makes the nuclear kinetic energy operator diagonal, thus simplifying the analysis. [/QUOTE]
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Forums
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Atomic and Condensed Matter
Confused about population transfer
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